Celebrate World Corrosion Awareness Day with 20% off eCourses and eBooks with code WCAD2024 at checkout!
High strength carbon steel tensile wires confined in the annulus of flexible pipes might experience corrosion when the annulus is flooded with water, either due to outer sheath breaches or to condensation of water molecules permeating from the bore through the inner sheath. Carbon dioxide (CO2) molecules may also permeate from the bore and reach the annulus, where it dissolves into water to form carbonic acid (H2CO3).
The influence of oxygen on the morphology and protectiveness of iron carbonate scales formed on carbon steel in CO2 environments at near-neutral pH was investigated. Specimens were tensioned in four-point bending jigs for stress corrosion cracking tests, and unloaded specimens were used for electrochemical tests. All specimens were exposed to CO2 aqueous solutions with and without dissolved oxygen, and corrosion rates were monitored by linear polarization resistance technique. Corrosion scales were characterized by scanning electron microscopy and X-ray diffraction, while the analysis of the corroded surface of the specimens after scale removal was carried out using scanning electron microscopy and optical profilometry. The iron carbonate scales were destabilized and became less protective in the presence of oxygen, which resulted in localized attacks, but no cracks were observed.
As long ago as 1973, design codes1 considered the possibility of hydrogen embrittlement due to CP. Between 1986 and 19952-4 the failure of DSS fasteners subjected to CP were reported. These were associated with high ferrite levels in the steel (approximately 70%) combined with precipitation hardening at 475°C to give the high levels of strength desired for fastener applications. At the same time, the susceptibility of DSS welds to hydrogen embrittlement had been reported5. Just like the fastener failures, the hydrogen cracking of welds was associated with high ferrite levels (70%), highly restrained joints and in the case of welds, high levels of diffusible hydrogen.
We are unable to complete this action. Please try again at a later time.
If this error continues to occur, please contact AMPP Customer Support for assistance.
Use this error code for reference:
Please login to use Standards Credits*
* AMPP Members receive Standards Credits in order to redeem eligible Standards and Reports in the Store
You are not a Member.
AMPP Members enjoy many benefits, including Standards Credits which can be used to redeem eligible Standards and Reports in the Store.
You can visit the Membership Page to learn about the benefits of membership.
You have previously purchased this item.
Go to Downloadable Products in your AMPP Store profile to find this item.
You do not have sufficient Standards Credits to claim this item.
Click on 'ADD TO CART' to purchase this item.
Your Standards Credit(s)
1
Remaining Credits
0
Please review your transaction.
Click on 'REDEEM' to use your Standards Credits to claim this item.
You have successfully redeemed:
Go to Downloadable Products in your AMPP Store Profile to find and download this item.
Proper surface preparation to create sufficient adhesion of a coating over the substrate is fundamentally important in the long-life performance of a protective coating. Abrasive blast cleaning provides a fast and well-established method of surface preparation, which utilizes energy generated by an air supply to deliver a mass of abrasive particles at certain speeds and volumes to impact the steel resulting in a cleaned surface. The method not only cleans the surface to remove rust, scale, paint, and similar contaminations, but also roughens the surface to produce mechanical and chemical adhesion for a coating. Therefore, abrasive blasting is the preferred method for preparing steel for the application of high-performance coatings and routinely used for achieving the required surface conditions prior to a coating work.