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Low alloy steels (LAS) are widely used in the marine and offshore oil and gas industry for various applications from bolting to large pressure containing heavy wall forgings. These materials are subject to various types of corrosion (general or uniform, pitting, crevice, etc.) and degradation in seawater environment. However, their selection for the applications, in comparison with stainless steels and corrosion resistant alloys, is justified due to their availability, manufacturability, proven service history, and lower cost.
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Several mechanisms including Hydrogen-Enhanced Localised Plasticity (HELP) and Hydrogen-Enhanced De-cohesion (HEDE) have been identified as contributing to the hydrogen embrittlement susceptibility of UNS N07718, depending upon microstructural particularities in the material.
With the rapid development of China's economy, energy and transportation industries have developed rapidly, and more and more oil and gas pipelines and urban rail transit have been built and put into use. Urban rail transportation systems, such as subways or light rail, generally use direct current traction and backflow through the rail. Because the track is not completely insulated from the earth, it is inevitable that some electric current will be discharged from the track to the earth to form stray electric current, which will cause interference to the surrounding metal components such as buried oil and gas pipelines.
Steel bars used in pre-stressed concrete structures are constantly subjected to tensile stress, and some steel bars have been reported to fracture due to hydrogen embrittlement. It is important to know the hydrogen embrittlement behavior in steel bars to prevent fracture.
Precipitation hardened (PH) Ni-based alloys have been utilized in oil and gas industry for decades. Among them, UNS1 N07718 because of its performance in sour wellbore fluids and in hydrogen charging environments has received the most attention for multiple upstream applications such as tubing hangers, production stab, multi-phase flow meter bodies, valve stems, etc. It has been reported that the alloy performance is generally acceptable for many applications up to 175 °C (350 °F) – 204 °C (400 °F) in the exposed wellbore environments such as sour production fluid, completion brine, and depending on metallurgical processing and microstructure externally exposed to SWCP at the seabed temperature.
Cesium formate (CsFo) brines have been used as the drilling and/or completion fluids in oil and gas wells in need of high-density fluids.1,2 Multiple studies on corrosion of steels and corrosion resistance alloys (CRA) in formate environments have been reported in the literature.2-8 It was known that the formate brines could undergo significant decomposition to form hydrogen when in contact with catalytic surfaces which CRA can act as. Therefore, there have been concerns that the CRA may catalyze the decomposition of formate brines to accelerate the generation of hydrogen which in turn may embrittle certain CRAs and endanger the relevant well equipment.
Hydrogen as a promising alternative energy source that is forecasted to potentially transform future power generation toward new-zero. However, its widespread adoption has proven challenging owing to difficulties around storage, transportation, and usage due to catastrophic failures i.e. hydrogen embrittlement (HE). This is particularly severe for high-strength structural steel that must be designed against fatal fractures; it is also relevant to parts that are not designed for hydrogen exposure due to the prevention of accidental spill or leakage.
Failure of a diffuser (with vanes, made from material P265GH) is investigated. The gas compressor was in service for over 10 years. The gas contained both CO2 and H2S. Relative humidity of the gas was 100 %. It was found that the diffuser was fractured in 3 locations.