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The major damage mechanisms for Precast Concrete Cylinder Pipe (PCCP) are well-known for both water transmission mains and wastewater force mains.
Rebars used in prestressed concrete structures are constantly subjected to tensile stress, and some rebars have been reported to fracture due to hydrogen embrittlement.1 It is important to know the hydrogen embrittlement behavior in rebars to prevent fractures. The effects of environmental conditions such as tensile stress, hydrogen content, and temperature on time to fracture have been evaluated individually;2,3 however, their combined effects have not been clarified. The purpose of this study is to experimentally clarify the relationship between time to fracture due to hydrogen embrittlement and environmental conditions to which the rebars are subjected.
Additively Manufactured Alloy UNS N07718 (AM 718) has been increasingly adopted for components in oilfield applications. AM 718 fabricated using laser powder bed fusion (LPBF) has demonstrated not only excellent mechanical performance, but also promising capabilities in critical services such as sour or hydrogen-generating conditions. In oilfield applications, it is generally felt that AM 718 should comply with API standard 20S4, and align with the requirements for wrought 718 in API 6ACRA.
While dedicated hydrogen pipelines have been present on the Gulf Coast of the US for decades, new application opportunities are opening up for transportation of hydrogen as a greener fuel. Some opportunities may be for newly built transportation lines while others may use existing natural gas pipelines that are converted to wholly or partially carry hydrogen. A normal part of operating a pipeline system is reconfiguring the system to add new pipes by making tie-in welds joining the new pipe to the wall of the existing pipe.
Precipitation hardened (PH) nickel-base alloys are frequently used as engineering materials in the Oil & Gas industry. They excel because of their outstanding combination of strength, toughness, and corrosion resistance. In that regard, alloy N07725 is of high interest as it offers better corrosion resistance than the widely used N07718, while also offering better high temperature strength than solid-solution nickel-base alloys.
AISI 4340 low-alloy steel (UNS G43400) is frequently used for critical bolting applications on subsea equipment in the oil and gas industry because of its ability to be heat treated to high strength levels while maintaining high toughness, even in large diameter bolting. However, several field incidents resulting from hydrogen embrittlement of AISI 4340 bolting have brought into question the maximum hardness that should be specified for low-alloy steel bolting and whether zinc electroplating can contribute to hydrogen embrittlement of low-alloy steel bolting in subsea applications.
In this evaluation, the relative hydrogen embrittlement resistance of AISI 4340 with different mechanical properties and surface conditions was determined using electrochemical pre-charging followed by step loading per ASTM F1624-121 in a 3.5% NaCl solution. The test specimens were round, notched tensile test bars stressed in uniaxial tension to simulate the load on a tensioned bolt. Testing was performed on material at two different strength levels with no coating, with zinc electroplate (both baked and un-baked), and with a phosphate coating to evaluate the effects of coatings. The tests were performed in air, in the NaCl solution at open circuit potential, and in the NaCl solution at -950 mV, -1050 mV, and - 1250 mV (Ag/AgCl) to evaluate the effects of different levels of cathodic protection.
Low alloy steels (LAS) are widely used in the marine and offshore oil and gas industry for various applications from bolting to large pressure containing heavy wall forgings. These materials are subject to various types of corrosion (general or uniform, pitting, crevice, etc.) and degradation in seawater environment. However, their selection for the applications, in comparison with stainless steels and corrosion resistant alloys, is justified due to their availability, manufacturability, proven service history, and lower cost.
Several mechanisms including Hydrogen-Enhanced Localised Plasticity (HELP) and Hydrogen-Enhanced De-cohesion (HEDE) have been identified as contributing to the hydrogen embrittlement susceptibility of UNS N07718, depending upon microstructural particularities in the material.