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51316-7109-Marine Crevice Corrosion Of Stainless Steel Alloys Under Biofilmed And Sterile Conditions

Picture for Marine Crevice Corrosion Of Stainless Steel Alloys Under Biofilmed And Sterile Conditions
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As part of a project to develop a database of seawater corrosion resistance including resistance to microbiologically-influenced corrosion (MIC) seawater, MIC exposure tests of five stainless steel alloys were undertaken for three and six month durations.

Product Number: 51316-7109-SG
ISBN: 7109 2016 CP
Author: James Stott
Publication Date: 2016
Industries: Maritime , Materials Selection and Design , Science of Corrosion
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As part of a project to develop a database of seawater corrosion resistance including resistance to microbiologically-influenced corrosion (MIC) seawater MIC exposure tests of five stainless steel alloys were undertaken for three and six month durations. Coupons of each metal which included crevices were exposed to marine conditions at a temperature of 30C in the presence of SRB biofilm under controlled laboratory conditions. Identical sets of coupons were exposed to nominally sterile seawater under the same conditions for the same time.Very severe crevice corrosion in the range 1 to 2 mm in 6 months was observed on specimens of stainless steel alloys UNS S30400 S31603 and lean Duplex S32101 exposed to the biofilm condition. A lesser but still severe amount of crevice corrosion to a maximum depth of ~0.5 mm was observed on Duplex alloy S31803 exposed biofilm conditions over the same period. Some significant crevice corrosion to maximum depth of 0.26 mm was also observed on the S32750 Superduplex material.The results for the nominally sterile control tests were very different to those of the biofilmed specimens. In nominally sterile seawater at the same temperature as the biofilmed coupons only the S30400 coupon specimens showed any crevice corrosion to a maximum depth of only 0.065 mm. This was ~20 times less than the depth of crevice corrosion on the biofilmed S30400 coupon. The S31603 and S32101 coupons showed only minor attack with a few small pits to a maximum depth of 0.059 mm and 0.021 mm respectively. The Duplex S31803 and Superduplex S32750 materials were free of any visible corrosion.A series of photographs and photo-micrographs are presented illustrating the morphology of the damage and the remarkable differences between specimens exposed to the biofilmed and sterile seawater environments.

Key words: downloadable, marine, seawater, microbial, MIC, bacteria, biofilm, stainless steel, duplex, Superduplex, UNS S31603, UNS S30403, UNS S32101, UNS S31803, UNS S32750, crevice, SRB, sulfate-reducing bacteria

As part of a project to develop a database of seawater corrosion resistance including resistance to microbiologically-influenced corrosion (MIC) seawater MIC exposure tests of five stainless steel alloys were undertaken for three and six month durations. Coupons of each metal which included crevices were exposed to marine conditions at a temperature of 30C in the presence of SRB biofilm under controlled laboratory conditions. Identical sets of coupons were exposed to nominally sterile seawater under the same conditions for the same time.Very severe crevice corrosion in the range 1 to 2 mm in 6 months was observed on specimens of stainless steel alloys UNS S30400 S31603 and lean Duplex S32101 exposed to the biofilm condition. A lesser but still severe amount of crevice corrosion to a maximum depth of ~0.5 mm was observed on Duplex alloy S31803 exposed biofilm conditions over the same period. Some significant crevice corrosion to maximum depth of 0.26 mm was also observed on the S32750 Superduplex material.The results for the nominally sterile control tests were very different to those of the biofilmed specimens. In nominally sterile seawater at the same temperature as the biofilmed coupons only the S30400 coupon specimens showed any crevice corrosion to a maximum depth of only 0.065 mm. This was ~20 times less than the depth of crevice corrosion on the biofilmed S30400 coupon. The S31603 and S32101 coupons showed only minor attack with a few small pits to a maximum depth of 0.059 mm and 0.021 mm respectively. The Duplex S31803 and Superduplex S32750 materials were free of any visible corrosion.A series of photographs and photo-micrographs are presented illustrating the morphology of the damage and the remarkable differences between specimens exposed to the biofilmed and sterile seawater environments.

Key words: downloadable, marine, seawater, microbial, MIC, bacteria, biofilm, stainless steel, duplex, Superduplex, UNS S31603, UNS S30403, UNS S32101, UNS S31803, UNS S32750, crevice, SRB, sulfate-reducing bacteria

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11351 The Corrosion of Superduplex Stainless Steel in Different Types of Seawater

Product Number: 51300-11351-SG
ISBN: 2011 11351 CP
Author: R Francis, G Byrne and G Warburton
Publication Date: 2011
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Superduplex stainless steels have been used in seawater systems since 1986 as castings and since 1990 as wrought product. The present paper describes some of the service environments commonly in use and the conditions that give rise to specific operating potentials. The limits of use under these conditions are described utilizing both laboratory and service experience.
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51316-7058-Galvanic Series in Seawater as a Function of Temperature Oxygen Content and Chlorination

Product Number: 51316-7058-SG
ISBN: 7058 2016 CP
Author: Dominique Thierry
Publication Date: 2016
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In this work, the open circuit potential of different stainless steel grades as well as nickel based and copper based alloys has been systematically measured in seawater under different experimental conditions. In particular the effect of temperature, oxygen content and chlorination level have been studied.
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51316-7127-Flow Accelerated Corrosion of Carbon Steel Pipe Carrying Hot Condensate Water in a Chemical Plant

Product Number: 51316-7127-SG
ISBN: 7127 2016 CP
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Multiple leaks occurred with a carbon steel pipe carrying hot condensate water (300F and 140 psi).  A root cause analysis was performed, including visual and metallographic examination of two failed samples chemical, analysis of weld metal and base metal and chemical analysis of water samples.  Results show that flow accelerated corrosion (FAC) was the responsible mechanism leading to the failures.
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