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Galvele introduced a new framework for localized corrosion with his seminal paper on acidification and chloride accumulation in pits & the need for a critical product of current density & pit depth to sustain this chemistry. This paper is to review the progress in these areas with a particular focus on repassivation potential.
~~Galvele introduced a new quantitative framework to think about localized corrosion through his seminal paper on acidification and chloride accumulation in pits and the need for a critical product of current density and pit depth to sustain this local chemistry. This concept introduced in 1976 holds good today but has been enhanced by the ability to conduct more complex computations better modeling of concentrated solutions that could be present in local areas and the ability to perform in-situ chemical analyses in pits. The purpose of this paper is to review the progress in these areas with a particular focus on repassivation potential as a criterion for stability of localized corrosion. The paper will discuss the use of repassivation potentials as a predictor of long-term occurrence of localized corrosion of various alloys the results of different reactive-transport modeling approaches in understanding local chemistry changes during repassivation and the use of different in-situ chemical analyses in understanding localized corrosion. The focus will be primarily on Fe-Ni-Cr-Mo alloys but other alloy systems will be mentioned as needed.
Key words: downloadable, Localized corrosion, pitting, crevice corrosion, repassivation potential, pH, chloride, stainless steels, Ni-base alloys
Bayesian networks (BN) are useful tools for corrosion modeling. This paper is a case study demonstrating how to perform Internal Corrosion Direct Assessment (ICDA) using BN modeling with limited data. A BN model was developed for ICDA of a 50 km refined oil pipeline. Internal corrosion probability of failure along the pipeline was assessed.
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This work presents a numerical model of the coupled interactions between temperature profile, electrolytic potential drop, and steady-state oxygen concentration gradient in soils surrounding buried pipelines.
Copper based waterborne wood preservatives increase the corrosion of metals embedded or in contact with the treated wood. We examine wood that was in contact with corroding metal with synchrotron based X-ray fluorescence microscopy (XFM) and X-ray Absorption Near Edge Spectroscopy (XANES) to test if the proposed corrosion mechanism is correct.