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This paper addresses the relationship between hardness and environmental cracking resistance in nickel base alloys. The work here builds on the presentation made to AMPP’s SC08 Fall 2021 meeting on October 19th.
The manufacturing and field experience of high strength low alloy (HSLA) steel plates produced by Thermo-Mechanical Controlled Process (TMCP) are well defined in industry standards and literature. The TMCP method consists of a well-prescribed rolling pass schedule followed by accelerated cooling that leads to a fine-grain microstructure with the desired mechanical properties of the produced plates.Quite recently, this TMCP process resulted in detrimental local variations with hidden hardness variations on pipe ID, so-called Local hard Zones (LHZ).
The current paper deals with a thorough analysis of these newly recognized LHZ with Scanning Electron Microscope (SEM) and Electron Back Scattering Diffraction (EBSD) investigations through the wall thickness of pipes. Internal diameter (ID) surface, intermediate zone and bulk metal microstructures showed an increase of a strong misorientation while approaching the ID. Thus, LHZ is characterized by the presence of lath and especially lower bainite type microstructures associated to high local hardness above the NACE MR 0175 / ISO 15156 limits for sour service applications.
Alloy 690 has been utilized since the late 1980s as a replacement for Alloy 600 in pressurized water reactors (PWR) pressure boundary components due to laboratory data indicating higher resistance to stress corrosion cracking (SCC). Although to date no SCC incidents have been reported on Alloy 690 components in service, the growing interest of extending the operation life of PWRs beyond 60 or even 80 years has raised concerns for the potential occurrence of long-range ordering (LRO) in Alloy 690 and its compatible weld metals.
Guidelines to prevent environmental cracking of weldments in carbon steel refinery equipment and piping. Welding processes: SMAW, GMAW, FCAW, GTAW and SAW.
Guías para prevenir formas de agrietamiento ambiental en uniones soldadas de equipos de acero al carbón en refinerías - recipientes presión, intercambiadores de calor, tuberías, cuerpos de válvulas y carcazas de bombas y compresores.