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This work evaluated chemical and electrical stability of commercially reference electrodes in contact with sand treated with vapor-phase corrosion inhibitors (VCIs). Several types of electrodes were tested, including Cu/CuSO4, bentonite-clay clad Cu/CuSO4, and bentonite-clay clad Zn/ZnSO4.
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This paper presents new applications of Volatile Corrosion Inhibitors (VCI) inside new and/or existing out-of-service pipelines. The system utilizes a combination of soluble and volatile corrosion inhibitors that are directly applied into the pipeline.
Corrosion control systems for the underside steel plates of above-ground storage tanks (ASTs) may not provide adequate protection. Volatile Corrosion Inhibitors (VCIs) reduce corrosion in this area and their effectiveness is presented in this paper.
Vapor corrosion inhibitor installation for cased crossing and aboveground storage tank bottoms at military facilities. Safety, testing, documentation and lessons learned. Also, NEC requirements where applicable.
Integrity management of corrosion under insulation (CUI) has historically and continues to be one of the biggest corrosion related challenges within the oil & gas, maritime, chemical and petrochemical industries.2 Corrosion of piping, associated flanges, pressure vessels and structural components from CUI is a commonly found phenomenon and if left undetected or not stringently managed can result in catastrophic leaks or explosions, equipment failure and periods of prolonged downtime due to repair or replacement. It is estimated around 40% to 60% of an operator’s pipeline maintenance budget is a result of CUI.3
The NACE TM0208-2018 Jar Test remains an industry-wide recognized standard for evaluating the vapor-inhibiting ability (VIA) of raw materials and finished products to provide off-contact corrosion protection of steel surfaces1. It is particularly useful for comparing the efficacy of different VCI chemistries, as well as for monitoring performance consistency between productions of VCI functionalized materials.
Volatile corrosion inhibitor (VCI) materials provide temporary corrosion protection for the surfaces of metal parts that are not in contact with the inhibitor. Temporary protection is afforded as long as there is a moderately sealed enclosure containing the metal parts and the source of the VCI, which may be in the enclosing package itself. The duration of protection may be months to years before the parts are removed from the enclosure and put to use, or before a more “permanent” coating such as paint is applied. The referenced NACE Standard Practice SP0487 includes VCI in the context of guidance and best practices for users of interim or temporary corrosion protection methods.
Metallic corrosion is a natural inevitable phenomenon defined commonly as the deterioration of metals due to reactions with their environments. The global cost of corrosion estimated by NACE in 2013 was found to be $2.5 trillion (USD), which is approximately 3.4% of the global gross domestic product (GDP). The two-year global study released at the CORROSION 2016 conference in Vancouver, B.C., Canada, assessed the economics of corrosion and the role of corrosion management in establishing best practices for the different industrial sectors. It found that implementing corrosion prevention best practices could result in global annual savings of 15-35 % of the cost of damage, which is equivalent to $375-875 billion (USD). These estimations excluded the cost of individual safety and environmental consequences from corrosion. Corrosion mitigation has been extensively researched. The methods of corrosion prevention include, but are not limited to, selection of the right material of construction, coatings, corrosion inhibitors, and cathodic protection.1,2
Top of line corrosion (TLC) is a degradation mechanism predominantly encountered in the oil and gas industry. Initiation of TLC requires a stratified flow regime with wet gas transportation and the existence of a significant temperature gradient between the hot fluid inside the pipeline and the colder external environment.1,2,3 This temperature difference results in the condensation of water vapor, present in the gas phase, onto the cooler, upper internal section of the pipeline. The condensed water can be particularly aggressive as it lacks dissolved salts (e.g. bicarbonates), some of which are able to buffer the bulk electrolyte, increasing the pH and suppressing corrosivity.4,5,6 The absence of such salts typically results in a very low pH condensate (<pH 4), often containing dissolved acidic gases, such as carbon dioxide (CO2) and hydrogen sulfide (H2S), and also acetic acid (HAc), which can cause severe degradation, particularly in the form of localized corrosion.5
Top of the line corrosion (TLC) is a phenomenon encountered in the transportation of wet gas, where temperature differences between the pipelines and the surroundings lead to condensation of water and subsequent metal degradation. This kind of corrosion occurs due to the condensation of saturated vapors present in the unprocessed gas stream which collects on the internal surface of the cold pipe wall. The condensed liquid contains hydrocarbons and water. It forms a thin film and/or droplets of liquid on the pipeline. The condensed water phase can be, at least initially, very corrosive to typical pipeline (made of carbon steel), because it contains dissolved acid gases (such as carbon dioxide [CO2] and hydrogen sulfide [H2S]) and organic acids (such as acetic acid [CH₃COOH]).1