AMPP Store - Products tagged with 'modeling'

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Life Extension of Offshore Field in The Santa Barbara Channel 2: Multi-Objective Optimization of Retrofit ICCP Anode Sled Placement Using Calibrated 3D Simulations

Product Number: 51323-19382-SG

Author: Matthew L. Taylor, Omar Rosas Camacho, Sami Abu-Zahra

Publication Date: 2023

$20.00

The life of offshore jacket structures can be extended up to 30 years towards the end of their design life by retrofits. For larger structures, and in unusual cases, semi-remote ICCP anode sleds are a favorable option compared to sacrificial anode cathodic protection (SACP) due to the high current output from each individual installation, reducing the time to install substantially. Anode sled locations are determined based on site plans, experience, survey data, and equations evaluating “remoteness” or “voltage rise” criteria.

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Managing Integrity And Corrosion Through Real-Time Prediction Modeling Approach – “Software Sensor” Concept

Product Number: 51322-18126-SG

Author: Slawomir Kus

Publication Date: 2022

$20.00

Safe and stable operation of the process plant through its life cycle is an ultimate target of any integrity management system. Over the last decades, a number of possible ways and systems for managing plant integrity were described and implemented.^1-4 A common path for all those efforts was to control and manage corrosion processes in a more-or-less systematic way by applying certain measures (monitoring techniques, material selection guidelines, operating procedures etc.) and performance indicators (remaining time-to-failure, inhibitor usage etc.). An effective corrosion and integrity management system, in theory, should be capable to “uncover” excessive corrosion incidents before serious damage occurs. Unfortunately, unexpected corrosion-related failures are still occurring in the petroleum industry.⁵ This situation stems predominantly from relatively poor data organization and management, leaving corrosion and key process information spread and hidden across different refinery functions and systems.

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Modeling Stress Corrosion Cracking With Explicit 3D Grain Microstructure

Product Number: ED22-17160-SG

Author: Benjamin S Anglin, Thomas W Web

Publication Date: 2022

$20.00

Stress corrosion cracking (SCC) of Type 304 stainless steel (304 SS) in elevated temperature (288 °C) high purity water is typically an intergranular (IG) process with cracks propagating along grain boundaries, which are mesoscopic entities relevant on the grain scale. It follows then that the nature of the grain boundaries plays a significant role in SCC. In fact, for IG SCC to occur three things must be present: 1) stress; 2) a corrosive environment; and 3) susceptible grain boundaries. SCC growth rate (SCCGR) equations for 304SS in high temperature, high purity water, test orientation, temperature, material composition, and sensitization.

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Next Generation Reinforced Concrete Corrosion Modeling With Interdependent Initiation And Propagation Stages

Product Number: 51321-16848-SG

Author: Alberto A. Sagues; Christopher L. Alexander

Publication Date: 2021

$20.00

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Predicting Hot Oil Corrosion: A Framework for Quantifying Reactive Organic Sulfur Compounds in Crude Unit Process Streams

Product Number: 51323-19105-SG

Author: Winston Robbins, Sridhar Srinivasan, Gerrit Buchheim

Publication Date: 2023

$20.00

In Corrosion/2021, the authors introduced a molecular mechanistic model that quantifies and predicts SNAPS corrosion rates. During Corrosion/2022, we presented the mechanistic corrosion prediction framework describing the molecular basis of the model’s reactions, kinetics, and mass transport of ROSC to vessel walls. In this molecular model, sulfidation corrosion is calculated for direct heterolytic reaction of ROSC with solid surfaces.

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Quantifying Effect of Hydrogen and Sulfur in Mitigating Free Fatty Acid Corrosion in Renewable Diesel Applications

Product Number: 51324-20864-SG

Author: Sridhar Srinivasan; Winston Robbins; Gerrit Buchheim

Publication Date: 2024

$40.00

Production of Renewable Diesel (RD) and Sustainable Aviation Fuels (SAF) from bio / natural oils has seen significant investment in recent years, stemming from worldwide government mandated need to reduce fossil fuel CO2 emissions. New investments have occurred in retrofitting / adapting existing refinery hydroprocessing infrastructure to process natural oils or coprocess natural oils blended with crudes to produce RD and SAF. This stems from the fact that natural oils have the hydrocarbon (HC) structures to fit within the mid-distillate fuel product such as diesel and aviation fuel as well as that these processes are optimized for removal of unwanted Sulfur and Oxygen removal. In Corrosion/2023, the authors introduced a molecular mechanistic model to quantify FFA corrosion as a function of temperature and FFA concentration. This model exploited the similarity of FFA to carboxylic acids, akin to naphthenic acids found in conventional refinery crude unit process streams, especially in case of unsaturated FFA. A key aspect of modeling corrosion for FFA is the inhibitive role of hydrogen in the presence of Iron sulfide species. While natural oils do not contain sulfur compounds, presence of reactive sulfur species such as thiols and sulfides in coprocessing applications provides an easy pathway to provide for the formation of a potentially protective nano barrier layer of FeS. Further, the presence of FeS acts as a catalyst towards dissociation of molecular H2 to atomic H and subsequent reduction of FFA through atomic hydrogen. A threshold H2 partial pressure is required to ensure hydrogen reduction of FFA is kinetically dominant when compared to acid corrosion of Fe. Residence time of acid is another key parameter that will impact propensity for corrosion and / or H2 inhibition and is considered in the development of the prediction model. A framework incorporating the effects of H2 partial pressure, residence time and reactive S concentration is proposed for assessing FFA corrosion for various commonly utilized natural oils in renewable applications.

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Quantifying High Temperature Corrosion in Renewable Diesel and Sustainable Aviation Fuel Production

Product Number: 51323-19457-SG

Author: Sridhar Srinivasan, Winston Robbins, Gerrit Buchheim

Publication Date: 2023

$20.00

In Corrosion/2021, the authors introduced a molecular mechanistic model that quantifies and predicts simultaneous naphthenic acid and sulfidation (SNAPS) corrosion rates. During Corrosion/2022, we presented the mechanistic corrosion prediction framework describing the molecular basis of the model’s reactions, kinetics, and mass transport of reactive organic sulfur compounds (ROSC) to vessel walls. In this molecular model, sulfidation corrosion is calculated for direct heterolytic reaction of ROSC with solid surfaces.

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The AA2024/CFRP Galvanic Couple Under A Dynamic Electrolyte Drop

Product Number: 51322-17686-SG

Author: R. Montoya, E. García-Lecina, J.M. Vega-Vega, J. Genesca

Publication Date: 2022

$20.00

The gap between fully immersed and ultra-thin film electrochemical measurements is wide, which suggests that the two conditions are independent of one another. There is a lot of work describing experiments, results, and trends regarding completely immersed electrochemical tests. However, in corrosion tests under thin electrolyte films, the information is not so abundant. A classical three-electrode cell used in conventional electrochemical tests cannot easily be scaled for immersion in electrolytes of micron thickness.

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Validating a Galvanic Corrosion Model under a Dynamic Electrolyte Droplet

Product Number: 51323-19015-SG

Author: R. Montoya, J.M. Vega-Vega, A. Ruiz-García, E. García-Lecina, J. Genesca

Publication Date: 2023

$20.00

As previously reported, the gap between electrochemical measurements for systems under bulk conditions and those under thin film layers of electrolyte is still important. Under thin film layers, it is not straightforward to take advantage of the typical three-electrode cell to electrochemically characterize a metallic surface under corrosion. Only a few localized electrochemical techniques are able to achieve measurements under thin films of moisture. It is important to bear in mind that the mechanism for corrosion under thin films is fully different from corrosion on bulk electrolytes and it is not valid to predict the behavior of the former system by extrapolating the latter.

Products tagged with 'modeling'

Association for Materials Protection and Performance