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Large underground, carbon steel tanks are used for interim storage of liquid radioactive waste. The current corrosion control program needs to be updated to account for the susceptibility to pitting corrosion of waste tanks due to the halide content of the secondary waste.
Large underground carbon steel tanks are used for interim storage of liquid radioactive waste at the Hanford site. The Hanford Waste Treatment and Immobilization Plant (WTP) is being constructed to treat the high-level waste (HLW) and low-activity waste (LAW) in the tank. The WTP LAW recycle stream will be generated by condensation and scrubbing of the LAW melter off-gas stream. A portion of this stream which will contain substantial amounts of chloride fluoride ammonia and sulfate ions may be returned to the tank farms for storage and evaporation. Presently there are no restrictions on the halide or sulfate concentrations of this return stream prior to transferring to the carbon steel waste tanks. Prior to initiating the process the susceptibility to pitting corrosion of waste tanks due to the halide contents of the return stream was investigated. Cyclic potentiodynamic polarization tests were utilized to determine the nitrite inhibitor requirements needed to safely store and process the return stream.
Key words: radioactive waste, carbon steel, pitting corrosion, electrochemical testing
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Update on recent experiences from laboratory tests performed at service conditions for geothermal applications. Incorporated in a catalogue of suitable materials for applications geothermal power plants. Users shall be enabled to have a basis for designing such facilities.
The purpose of this review is to discuss environmental effects, especially hydrogen sulfide and carbon dioxide on pitting susceptibility of low alloy steels and corrosion resistant alloys.