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06576 PREDICTION AND ASSESSMENT OF AMMONIUM BISULFIDE CORROSION UNDER REFINERY SOUR WATER SERVICE CONDITIONS

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This paper summarizes results of a joint industry program (JIP) to address ammonium bisulfide (NH 4 HS) corrosion in H 2 S-dominated alkaline sour waters typically found in refinery services such as the reactor effluent air cooler (REAC) systems of hydroprocessing units.

Product Number: 51300-06576-SG
ISBN: 06576 2006 CP
Author: Richard J. Horvath, Michael S. Cayard, Russell D. Kane
Publication Date: 2006
Industry: Materials Selection and Design
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This paper summarizes results of a joint industry program (JIP) to address ammonium bisulfide (NH 4 HS) corrosion in H 2 S-dominated alkaline sour waters typically found in refinery services such as the reactor effluent air cooler (REAC) systems of hydroprocessing units. The impacts of several process variables on corrosion were quantified. Key learnings support a paradigm shift from the rules of thumb previously applied to these systems. Data collected were used to develop a software tool to predict the corrosion rate of 14 materials evaluated in the program.

Keywords: sour water, ammonium bisulfide, NH 4 HS, hydrogen sulfide, H 2 S, partial pressure, isocorrosion diagram, temperature, chloride, hydrocarbon, velocity, wall shear stress, ammonium polysulfide, APS, imidazoline, materials selection, software, reactor effluent air cooler, REAC, hydroprocessing, refining

This paper summarizes results of a joint industry program (JIP) to address ammonium bisulfide (NH 4 HS) corrosion in H 2 S-dominated alkaline sour waters typically found in refinery services such as the reactor effluent air cooler (REAC) systems of hydroprocessing units. The impacts of several process variables on corrosion were quantified. Key learnings support a paradigm shift from the rules of thumb previously applied to these systems. Data collected were used to develop a software tool to predict the corrosion rate of 14 materials evaluated in the program.

Keywords: sour water, ammonium bisulfide, NH 4 HS, hydrogen sulfide, H 2 S, partial pressure, isocorrosion diagram, temperature, chloride, hydrocarbon, velocity, wall shear stress, ammonium polysulfide, APS, imidazoline, materials selection, software, reactor effluent air cooler, REAC, hydroprocessing, refining

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Picture for 10349 Prediction and Assessment of Ammonium Bisulfide Corrosion Under Refinery Sour Water
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10349 Prediction and Assessment of Ammonium Bisulfide Corrosion Under Refinery Sour Water Service Conditions-Part 2

Product Number: 51300-10349-SG
ISBN: 10349 2010 CP
Author: Richard J. Horvath, Vishal V. Lagad, Sridhar Srinivasan and Russell D. Kane
Publication Date: 2010
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This Phase II work in NH3-dominated sour waters studied the impact of several process variables including NH4HS concentration, NH3 partial pressure, H2S partial pressure, temperature, cyanide concentration, and velocity (wall shear stress).
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Prediction and Assessment of Ammonium Bisulfide Corrosion Under Refinery Service Conditions - Part 3

Product Number: 51317--8929-SG
ISBN: 8929 2017 CP
Author: Richard Horvath
Publication Date: 2017
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Summarizes results from Phase III of the joint industry program (JIP) on refinery alkaline sour water (ammonium bisulfide) corrosion. Phase III included a comprehensive engineering analysis of data from all three phases of the Sour Water JIP.
Picture for 06577 PREDICTION OF AMMONIUM BISULFIDE CORROSION
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06577 PREDICTION OF AMMONIUM BISULFIDE CORROSION AND VALIDATION WITH REFINERY PLANT EXPERIENCE

Product Number: 51300-06577-SG
ISBN: 06577 2006 CP
Author: Richard J. Horvath, Russell D. Kane, Vishal V. Lagad, Michael S. Cayard, Walter G. Giesbrecht
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