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Previously, precipitation of SI and Ca2+ was investigated. Similar work has also been performed by other researchers. The current paper presents corresponding experimental results where the binding of divalent cations Ca2+ and Sr2+ to 9 phosphonate SIs at pH 8.5, 95oC is investigated.
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Microbiologically influenced corrosion has been attributed to the activity of sulfate reducing and acid producing bacteria. Advances in DNA isolation and sequencing have revealed that these classes of bacteria often represent only a small portion of the corrosive microbial population present in the oil and gas environment.
This work presents a numerical model of the coupled interactions between temperature profile, electrolytic potential drop, and steady-state oxygen concentration gradient in soils surrounding buried pipelines.
Copper based waterborne wood preservatives increase the corrosion of metals embedded or in contact with the treated wood. We examine wood that was in contact with corroding metal with synchrotron based X-ray fluorescence microscopy (XFM) and X-ray Absorption Near Edge Spectroscopy (XANES) to test if the proposed corrosion mechanism is correct.
Bayesian networks (BN) are useful tools for corrosion modeling. This paper is a case study demonstrating how to perform Internal Corrosion Direct Assessment (ICDA) using BN modeling with limited data. A BN model was developed for ICDA of a 50 km refined oil pipeline. Internal corrosion probability of failure along the pipeline was assessed.
Galvele introduced a new framework for localized corrosion with his seminal paper on acidification and chloride accumulation in pits & the need for a critical product of current density & pit depth to sustain this chemistry. This paper is to review the progress in these areas with a particular focus on repassivation potential.
As part of a project to develop a database of seawater corrosion resistance including resistance to microbiologically-influenced corrosion (MIC) seawater, MIC exposure tests of five stainless steel alloys were undertaken for three and six month durations.
Fatigue and fracture performance of UNS N07718 (718) and UNS N07716 (625+) in sour environments over a range of temperatures (300 to 400°F) and chloride concentrations (0.15wt% to 25wt% NaCl). Rising displacement fracture toughness test performed in a range of environments.
The case study demonstrates different approaches towards what went wrong and why on pressure safety valve susceptible to MIC growth. The Eocene Sub Centre-1 Shipping Pump discharge header connected pressure safety valve (01PSV172) reported leaking from the body and POD requested Asset Integrity Division to conduct Root Cause Analysis with recommendation.
There are advantages to Post-tensioned (PT) concrete construction compared to conventional reinforcement. However, corrosion caused tendon failures have recently been reported d/t chemically and/or physically deficient grout. A predictive model has been developed that projects onset and rate of wire and strand fractures.
The concept of using physics-based models for corrosion monitoring is still new although corrosion monitoring by use of hardware coupons and probes is well recognized. This paper describes the application in downstream related to crude unit overhead and demonstrates how the monitoring concept can be used and its benefits.
This study presents an overview of a number of factors influencing the pitting corrosion of Ti in aggressive environments. Effects of temperature and metal cations on pitting corrosion of Ti.