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This paper describes the range of copper alloys in marine service today and the evolution of applications which include ships' cannon and hull sheathing in 18th and 19th century and condenser and seawater piping requirements which spurred concentrated investigations in the 20th century.
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In this paper, a new concept named CP by distributed sacrificial anodes (DSA) is presented. The main principle of CP by DSA is to convert cathode area to anode area by distributing anode mass over the surface of the equipment to be protected.
In this work, the effect of Tungsten on the precipitation kinetics of a 25% Cr SDSS, namely, UNS S32760 was quantified by constructing Time-Temperature-Transformation (TTT) diagrams.
Stainless steels have been used for a wide range of applications in seawater. They are known to be susceptible to localized corrosion under given conditions. This is often the limiting factor for the use of stainless steels for seawater applications.
Cathodic protection is used in addition to organic coatings to ensure the integrity of offshore and onshore buried structures against corrosion. The cathodic protection efficiency is usually ensured by keeping the potential of the structure to be protected in a narrow range following standard recommendations such as ISO 15589-1 and/or NF EN 12954. For onshore buried structures, this potential range is limited by the protection potential Ep and the limit potential El.
There have been several studies and publications over the past decade that clearly illustrate how initial assumptions about monopile interiors being perfectly sealed compartments were not correct in practice. Oxygen ingress through various points in the monopile contributes to persistent internal corrosion, and planned inspections are also opportunities to introduce fresh oxygen into the monopile. The replenishment of oxygen has been found to continue the corrosion reaction between the monopile wall and entrapped water.
In natural seawater, microorganisms can fix, grow and develop on practically any surface, including stainless steels, which may cause industrial issues such as microbial induced corrosion, loss of heat transfer efficiency, or undesired colonization from macro-fouling. In particular, the presence of a biofilm on passive alloys such as stainless steels or nickel-based alloys can strongly enhance the cathodic reactions such as reduction of dissolved oxygen, and shift the open-circuit potential (OCP) to the noble direction.This results in an increase in OCP, also called cathodic depolarization or biofilm-induced ennoblement, and affects the risk of localized corrosion, since the critical pitting or crevice potential can be exceeded.
Literature on cathodic protection (CP) in the ocean at depths greater than 300 m (1,000 ft). Reports extensively on deep water field test results and operating experiences.