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A technique capable of producing effective (up to 98% efficient) corrosion inhibitors via chemical modification of vegetable oils. The advantage of this technique is the one pot approach which drastically cuts costs. The inhibitors were tested in their ability to reduce corrosion in stirred, aerated seawater, a highly corrosive environment.
the synthesis of amide modified fatty acid corrosion inhibitors is reported.the synthetic routeuses a novel one pot strategy drastically reducing the synthesiscost. the reaction was shown to work using TLC spotting and FTIR analysis. the product without clean up - again achieving significant cost reductions was able to reduce corrosion in aerated stirred seawater by a factor of over 85 corrosion rate reduction from over 100 mpy to less than 1 mpy is reported.several different vegetable oils were converted into amides using a range of amines.
Key words: corrosion inhibitor synthesis, linear polarization resistance, aerated seawater
It has been shown that when calcium and phosphate, used with an oxidizing agent that the two inhibiting mechanisms, calcium phosphate and azole, compete for the surface. By identifying the surface chemistry, new inhibitors were developed to target surface chemistry of yellow metals.
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This paper describes a method of exploiting the critical micelle concentration (CMC) of the corrosion inhibitors to show that the use of CMC can be used as a laboratory screening method for corrosion inhibitor selection.
The issue of induced AC current corrosion and its mitigation for buried pipelines continues. A review of the design methods and mitigation technologies used in the past, and those recently developed and continue to evolve, to meet the AC mitigation challenges faced by buried pipeline operators.