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Mechanistic information was obtained employing such electrochemical techniques as linear polarization, electrochemical frequency modulation and potentiodynamic polarization while using a rotating cylinder electrode system under CO2 corrosion conditions.
Information about the corrosion inhibition mechanism of multi-components blends and of their respective individual components is vital to identify the synergistic interactions needed to maximize performance. The mechanistic information was obtained employing such electrochemical techniques as linear polarization (LPR) electrochemical frequency modulation (EFM) and potentiodynamic polarization while using a rotating cylinder electrode (RCE) system under CO2 corrosion conditions. The employed electrochemical methods allow determination of anodic cathodic or mixed corrosion inhibition mechanisms. The studied individual corrosion inhibitor components included sulfur containing compounds an imidazoline a quaternized amine and a phosphate ester. Binary combinations of the individual components were also studied to correlate the results obtained for the individual components with the inhibition mechanism of blends identifying potential synergistic interactions.
Keywords: CO2 corrosion, corrosion inhibition, mechanisms
The NORSOK M-506 is an empirical model based on experiments undertaken in a single phase water flow loop. The data is from experiments with low content of iron ions in the water phase, and the model is thus regarded to give a fair representation of the maximum corrosion rate in a CO2 corrosion controlled system.
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The literature has been reviewed with respect to information gained in the recent 20 years on CO2 corrosion of materials used in the oil and gas industry. The paper discusses the effect of materials related, medium-related and interface-related parameters on general (uniform) and localized corrosion. Part II