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In this paper, the CP current distribution with changing resistivities and the area of influence required to meet effective CP criteria, is studied. The results indicate that the tank pad electrolyte resistivity plays a significant role in achieving uniform CP current distribution. The paper also explores the use of Vapor Corrosion Inhibitor (VCI) and its effect on electrolyte resistivity and the resulting CP current distribution.
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Bis-Phenol A epoxy resin-based coatings are known for excellent corrosion and chemical resistance. Limitations of this class of coatings are poor flexibility, thermal stability and weather resistance. Traditional siloxane resins are commonly used in the industry to improve the thermal and weather resistance of bis-Phenol A epoxy coatings. In addition, organo-functional silicone polymers have been used to provide improved flexibility, but create recoatability issues.
NACE MR0175 / ISO 15156 document part 2 provides material requirements for selecting cast irons and low-alloy steels for sour environments.1 Figure 1 is reproduced from this standard and describes different regions of environmental severity for Sulfide Stress Cracking (SSC): service in region 0 being the least susceptible to cracking, even for very sensitive materials, and region 3 being the worst.
In Upstream, CRAs (Corrosion Resistant Alloys) are widely selected to handle seawater and brines in piping, valves, pumps, heat exchangers, vessels, and seawater injection1-4. Also, disposal of produced water is commonly performed through injection into spent fields. Water from a variety of sources including produced water, seawater and surface/fresh water may also be injected to create pressure drive for existing fields. Usually dissolved oxygen (DO) is not fully controlled when there are multiple sources of injection water and sometimes even possibility of injection of fully oxygenated water exists. For oxygenated seawater, the PREN (Pitting Resistance Equivalent Number = %Cr + 3.3 *(%Mo + 0.5 %W) + 16 %N) shall be >40 and limits are applied to the temperature4. Other applications involve Solid CRA or cladded production pipelines which may get flooded with seawater during installation and precommissioning.
HIGH-TEMPERATURE HYDROGEN ATTACK (HTHA) of steels is an extremely interesting topic in petrochemical industrial applications while a predictive physical model still does not exist. A number of studies carried out in the world are unambiguous confirmation of that statement. Bearing in mind multiple effects of hydrogen in certain metals the specific mechanism of high-temperature hydrogen attack embrittlement is manifested depending on the experimental conditions.The susceptibility of ASTM 204 Gr A steel to hydrogen-assisted cracking of refinery reactor retired was evaluated by mechanical fracture mechanics specimens. The material of zone with indication and zone without indications of the reactor was evaluated. Were loaded in tension and impact mechanical test to evaluate the probability of occurrence of the hydrogen-assisted cracking phenomenon. Fractography NDT and SEM-EDX analysis carried out on the fracture surfaces of the ruptured beams revealed was no evidence of the mechanisms of the crack propagation. Under both conditions the failure was cavity coalescence accommodated with plastic deformation. The results didn´t show the influence of hydrogen-induced embrittlement on the initiation of the fracture and the plasticity of the crack tip during the propagation of the crack where the latter becomes localized and uniform over the fracture surface. From the observations a three-stage crack propagation and lamination process and are proposed. Also the fracture toughness of the samples was evaluated by linear elastic fracture mechanics and the validity of the results are discussed. This result was very important to the refinery to develop plan inspections and make sound operations decisions based on the best available techniques.Keywords: Carbon steel corrosion HIGH TEMPERATURE HYDROGEN ATTACK (HTHA)
Improved selection of testing protocols for corrosion coatings, along with proper interpretation of the results, allows for a better representation of how coatings will perform in service. A review of several types of corrosive service environments is presented, including the testing normally performed, along with a more in depth look at how to quantify performance variables in a rating system based on individual test results.
Sulfur and acidic impurities in crude oils pose serious hot oil corrosion problems in crude distillation units (CDU) and associated vacuum distillation units (VDU), especially with the increase in processing of lowquality, opportunity crudes. In the range of 200-400˚C, reactive sulfur compounds cause sulfidation corrosion of ferritic carbon and chrome steels in CDU, VDU, and front ends of downstream units operating at hot oil temperatures. Over the same temperature range, naturally occurring carboxylic acids in crudes can be so aggressive that higher alloy, austenitic stainless steels containing >2.5% Mo are required for processing high acid oils.
As a means of surface preparation for protective coatings, abrasive blasting provides proper surface roughness and increases the surface area, which are critical in achieving physical and chemical adhesion between steel surface and organic coatings. For application of high-performance coating in a new shipbuilding, the abrasive blasting cleaning is widely favored primarily because of its economic and performance benefits. The abrasive blasting, however, also requires the significant amount of labor hour, whereas its efficiency mainly depends on the blaster’s skill.
Epoxy-based coating used in the ships and marine structures can be quickly degraded after only a short period of exterior exposure. The weathering defects such as discoloration, chalking and gloss reduction are originated from a photo-oxidation of aromatic group in the epoxy resin under the UV light. Weather resistance coatings such as polyurethane and polysiloxane require more work due to the short over-coating interval and low compatibility with primer coating layers.