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Picture for Develop Test and Validate a Corrosion Monitoring Cell to Quickly Evaluate Effectiveness of the Corrosion Control Measures
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Develop Test and Validate a Corrosion Monitoring Cell to Quickly Evaluate Effectiveness of the Corrosion Control Measures

Product Number: 51319-12841-SG
Author: Xihua He
Publication Date: 2019
$20.00

Aboveground storage tanks (ASTs) are widely used in the oil and gas and nuclear industries. These are typically constructed of carbon steel bottoms and shells with the bottoms susceptible to corrosion. Corrosion control measures include cathodic protection (CP) systems various levels of vapor corrosion inhibitors (VCIs) and combinations of VCIs CP and possibly biocides. The objective of this project was to develop test and validate an ultrasonic testing (UT) resonance probe and a corrosion monitoring cell to quickly evaluate the effectiveness of corrosion control measures with a focus on measures that involve CP alone and a combined application of CP and VCIs. The UT probe is an electromagnetic acoustic transducer (EMAT) used to generate ultrasonic shear waves for a resonance-based measurement approach. Three tests with the UT probe attached to the back of the carbon steel coupon set on wet sand were conducted in parallel. Test 1 started at open circuit (i.e. no CP) without any corrosion control measures followed by −850 mVCSE CP application later. Test 2 started with −850 mVCSE CP application followed by an open circuit. Test 3 started with both −850 mVCSE CP and VCI application followed by an open circuit. The posttest coupons were cleaned and scanned by a laser profilometer for corrosion depth measurement which was compared to the UT probe data.The resonance sensors successfully detected the onset and progress of corrosion from Cells 1 and 2 as CP was enabled and disabled. The absence of corrosion in Cell 3 also was clearly detected. The fundamental accuracy of the sensors was shown to be on the order of 1–3 µm when the surface being measured is very uniform. However it was not possible to make a quantifiable correlation between the corrosion profiles and the estimates from the sensors. When located over a non-uniform surface the sensors underestimated the amount of thickness loss likely due to scattering effects from feature scale lengths as small as or smaller than the ultrasonic wavelengths used as well as the variation in corrosion depths. Potential research is needed to understand the effects of variations in the surface that are small compared to the ultrasonic beam and even the ultrasonic wavelength. The adhered corrosion product on the coupons also may have affected the thickness readings because some of the ultrasonic beams were likely reflected from the corrosion/air interface in addition to the metal/corrosion interface. Further investigation would be required to determine if this was a significant factor.

Picture for Developing Vapor Phase Corrosion Inhibitors for Aluminum Alloys in Ethylene Glycol Coolant Solutions
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Developing Vapor Phase Corrosion Inhibitors for Aluminum Alloys in Ethylene Glycol Coolant Solutions

Product Number: 51324-20382-SG
Author: Behzad Bavarian; Lisa Reiner
Publication Date: 2024
$40.00
Picture for Development and Field Application of a New Bacteria Monitoring Technique
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Development and Field Application of a New Bacteria Monitoring Technique

Product Number: 51319-13158-SG
Author: Alyn Jenkins
Publication Date: 2019
$20.00

Accurate bacteria population monitoring is important in oil and gas fields to mitigate microbiologically influenced corrosion (MIC) prevent reservoir souring and optimize biocide treatment strategies. Serum serial dilution testing (SSDT) is a flawed yet widely accepted traditional method for bacteria testing in the oil and gas industry. The serum bottle test is cumbersome to perform correctly in the best of conditions and impractical to use in most if not all oil and gas field applications. The SSDT culture method returns an indirect estimate of bacteria populations that are often misleading and inaccurate due to basic assumption of the test and users attempts to stream line the method.It is important for operators to understand the drawbacks of the SSDT method and be aware that alternative accurate field ready techniques for bacteria population measurements are available. This paper reports the work performed to a develop a new method to detect bacteria in oil and gas fields that is used to select test and apply fit for purpose bacteria control chemicals.The new methodology has many advantages over other commonly used methods such as the SSDT and ATP tests. The new technique provides a rapid bacteria measurement that can be performed wholly at the well site with real time results. The method gives highly accurate data simple to use and is compatible with oilfield production chemicals fluid chemistries and system microbiology. The approach uses a bacteria metabolism based assay technique that utilizes fluorescence spectroscopy to obtain a fluorescence value that is proportional to the total number of living bacteria present in a sample. However the new method is unique in that the user converts the fluorescence value into meaningful data such as colony forming units per mL or even number of equivalent bug bottle turns. The conversion is based on the results of thousands of experiments comparing the fluorescence value with accurate laboratory bacteria measurements (e.g. plate counts and nucleic acid base testing) performed on field waters from a wide variety of sources.The new technique has been used in many oilfields throughout the world and several case histories are presented where the technique has been used to successfully optimize biocide treatments. This new approach to bacteria monitoring is unique and allows immediate real-time post treatment testing to ensure biocide applications are effective.