Environmental and material limits specified in ANSI/NACE MR0175/ISO15156-3:2015 restrict this use of
austenitic stainless steel alloys under sour conditions typically encountered in thermal in-situ oil sand
operations. This paper is a follow up study to one presented in 2016 (NACE-2016-7892), where C-ring
testing was conducted to evaluate the susceptibility of austenitic stainless steels to conditions simulating
a severe downhole environment; i.e. 230 °C, pH of 3.5, and variable chloride concentrations and H2S
partial pressures. Prior results indicated that after 720 hours of exposure, material did not show any
cracking when tested at 10,000 mg/L Cl- and 1,000 kPa pH2S, and at 50,000 mg/L Cl- and 100 kPa pH2S.
In recent testing, three heats of UNS S30403 were tested under the same environmental conditions
above and cracking was observed in some heats, suggesting borderline resistance to cracking under
these severe conditions and unsuitability per ANSI/NACE MR0175/ISO15156-3:2015. Additional C-ring
testing was performed in a less severe environment consisting of 230 °C, pH of 5, a chloride concentration
of 10,000 mg/L and 100 kPa pH2S, where the same three heats of UNS S30403 demonstrated no
cracking.