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51315-5595-Use of Electrochemical Techniques to Determine the Degree of ?-phase Precipitation in Type 25Cr SDSS

Picture for Use of Electrochemical Techniques to Determine the Degree of ?-phase Precipitation in Type 25Cr SDSS
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Product Number: 51315-5595-SG
ISBN: 5595 2015 CP
Author: Roy Johnsen
Publication Date: 2015
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Corrosion resistant alloys (CRAs) used in subsea pressure-retaining components must be compatible with production fluids and resistant to pitting and crevice corrosion in seawater. Whereas materials selection in production environments is governed by well-established international standards such as ISO 15156 much debate still exists as of how to determine the seawater localized corrosion resistance of higher grade CRAs such as duplex and super duplex stainless steels (DSS and SDSS respectively).While most industry specifications rely on the ASTM G48 standard to determine localized corrosion resistance for duplex and super duplex stainless steels there is no consensus on surface finish prior testing (e.g. grinding or pickling) and test temperature (e.g. 50 °C in NORSOK 630 versus 40 °C in ASTM A923). Moreover it is unclear whether existing procedures are sensitive enough to determine the onset of deleterious phases such as ?-phase and chromium nitrides.The objective of this investigation was to quantify the seawater pitting corrosion resistance of a type 25Cr SDSS (UNS S32750) and its correlation with: i) alloy’s microstructure and ii) surface finish before testing. Cyclic potentiodynamic polarization (CPP) testing was used to determine the effect of different ?-phase volume fractions on the corrosion response of the system. CPP results were then compared against industry standard practices based on the ASTM G48 Method A test. In addition CPP tests were conducted at various temperatures ranging from 25 to 90 ? to determine the effect of deleterious phases on critical pitting temperature (CPT) and overall localized corrosion resistance.
Corrosion resistant alloys (CRAs) used in subsea pressure-retaining components must be compatible with production fluids and resistant to pitting and crevice corrosion in seawater. Whereas materials selection in production environments is governed by well-established international standards such as ISO 15156 much debate still exists as of how to determine the seawater localized corrosion resistance of higher grade CRAs such as duplex and super duplex stainless steels (DSS and SDSS respectively).While most industry specifications rely on the ASTM G48 standard to determine localized corrosion resistance for duplex and super duplex stainless steels there is no consensus on surface finish prior testing (e.g. grinding or pickling) and test temperature (e.g. 50 °C in NORSOK 630 versus 40 °C in ASTM A923). Moreover it is unclear whether existing procedures are sensitive enough to determine the onset of deleterious phases such as ?-phase and chromium nitrides.The objective of this investigation was to quantify the seawater pitting corrosion resistance of a type 25Cr SDSS (UNS S32750) and its correlation with: i) alloy’s microstructure and ii) surface finish before testing. Cyclic potentiodynamic polarization (CPP) testing was used to determine the effect of different ?-phase volume fractions on the corrosion response of the system. CPP results were then compared against industry standard practices based on the ASTM G48 Method A test. In addition CPP tests were conducted at various temperatures ranging from 25 to 90 ? to determine the effect of deleterious phases on critical pitting temperature (CPT) and overall localized corrosion resistance.
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Picture for Effect of Tungsten on Pitting and Crevice Corrosion of Type 25Cr Super Duplex Stainless Steel
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51316-7308-Effect of Tungsten on Pitting and Crevice Corrosion of Type 25Cr Super Duplex Stainless Steel

Product Number: 51316-7308-SG
ISBN: 7308 2016 CP
Author: Roy Johnsen
Publication Date: 2016
$20.00

To examine the effect of Tungsten (W) on localized corrosion of 2 superduplex stainless steels (SDSS)- high & low-W. Both plain samples (pitting corrosion) and samples with artificial crevices (crevice corrosion) were exposed. Tests in 3.50-wt% NaCl solution or natural seawater. T= 30 to 90°C.
Picture for Influence of tungsten on passivity breakdown and repassivation of 25Cr super duplex stainless steels
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51318-11102-Influence of tungsten on passivity breakdown and repassivation of 25Cr super duplex stainless steels

Product Number: 51318-11102-SG
Author: Cristian Torres / Mariano Kappes / Roy Johnsen / Mariano Iannuzzi
Publication Date: 2018
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Two super duplex stainless steels were investigated: a W-free (UNS S32750) and a 2.1 wt% W-containing (UNS S39274) grade. Goals: To study localized corrosion resistance of super duplex stainless steels and how W affects the same.
Picture for 51318-11288-Bridge Coating Operation and Maintenance Planning
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51318-11288-Bridge Coating Operation and Maintenance Planning

Product Number: 51318-11288-SG
Author: Russell Draper / Dr. Mekdam Nima / Frances Wee
Publication Date: 2018
$20.00

This paper describes a bridge coating operation and maintenance manual that was developed for the City of Vancouver which operates and maintains an inventory of 33 bridges with coated steel elements.
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