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As previously reported, the gap between electrochemical measurements for systems under bulk conditions and those under thin film layers of electrolyte is still important. Under thin film layers, it is not straightforward to take advantage of the typical three-electrode cell to electrochemically characterize a metallic surface under corrosion. Only a few localized electrochemical techniques are able to achieve measurements under thin films of moisture. It is important to bear in mind that the mechanism for corrosion under thin films is fully different from corrosion on bulk electrolytes and it is not valid to predict the behavior of the former system by extrapolating the latter.
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