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The gap between fully immersed and ultra-thin film electrochemical measurements is wide, which suggests that the two conditions are independent of one another. There is a lot of work describing experiments, results, and trends regarding completely immersed electrochemical tests. However, in corrosion tests under thin electrolyte films, the information is not so abundant. A classical three-electrode cell used in conventional electrochemical tests cannot easily be scaled for immersion in electrolytes of micron thickness.
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As previously reported, the gap between electrochemical measurements for systems under bulk conditions and those under thin film layers of electrolyte is still important. Under thin film layers, it is not straightforward to take advantage of the typical three-electrode cell to electrochemically characterize a metallic surface under corrosion. Only a few localized electrochemical techniques are able to achieve measurements under thin films of moisture. It is important to bear in mind that the mechanism for corrosion under thin films is fully different from corrosion on bulk electrolytes and it is not valid to predict the behavior of the former system by extrapolating the latter.