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Picture for Investigating the Interaction of Brine Solutions and Diluted Inhibited HCl Acid on Coiled Tubing Steel Corrosion
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Investigating the Interaction of Brine Solutions and Diluted Inhibited HCl Acid on Coiled Tubing Steel Corrosion

Product Number: 51320-14596-SG
Author: N. Chkolny, J. Burns, D. Maley, C. Wiggins
Publication Date: 2020
$20.00

Coiled tubing is defined as a continuous tubular product that is used for oil and gas well interventions. Its popularity continues to grow due to its versatility and speed of operation. Though superior grades of metal alloys exist in terms of corrosion resistance, coiled tubing operations primarily employ high-strength low-alloy steels because of their availability, lower cost and weldability. The low-alloy steel can also be thermo-mechanically controlled to elicit specific material properties, such as yield strength and ductility. These coiled tubing steels are often introduced into potentially corrosive downhole conditions, therefore proper testing must be completed to ensure adequate corrosion protection prior to job execution. Downhole corrosive conditions often encountered include; oxygen saturated fluids, elevated temperatures, exposure to oxidizing agents, hydrochloric acid and highly concentrated brines. Often these fluids will be recirculated in a closed loop system, consistently re-exposing equipment to potentially damaging conditions. Frequently, these challenging conditions faced are tested individually with pressurized mass loss coupon testing at bottom hole conditions. However, due to a recent coiled tubing incident in which the coiled tubing pipe had completely parted downhole, the post-job incident investigation involving SEM and metallographic analysis revealed pitting corrosion throughout the tubing, despite the pre-job testing performed indicating adequate acid corrosion protection for the entirety of the job. A literature review indicated very little research was available involving the possible interaction of brine solutions and diluted acid on coiled tubing carbon steels. This paper aims to investigate the possible corrosive interactions between salt brines and inhibited acid blends at elevated temperatures on high grade coiled tubing coupon samples through metallographic examinations and mass loss tests in pressurized heated cells. Coiled tubing coupons will be exposed to a variety of acid blends diluted with a 10% brine (8% wt NaCl and 2% wt CaCl2) or fresh water to investigate the possibility of corrosion enhancement between saline fluids in a diluted acid system. 

Picture for Investigation of the Corrosion Performance of Stainless Steel and Low Alloy Steel Sucker Rod Materials in Aggressive Environments
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Investigation of the Corrosion Performance of Stainless Steel and Low Alloy Steel Sucker Rod Materials in Aggressive Environments

Product Number: 51320-14321-SG
Author: Aleksey Shakhmatov, Oscar Martinez, Robert Badrak, Sergey Kolesov, Rodrigo Barreto, William Howie
Publication Date: 2020
$20.00

The corrosion resistance of sucker rod materials can be a significant concern, especially in aggressive service environments with high acid gas concentrations. Corrosion-related failures have been associated with increased levels of produced hydrogen sulfide (H2S) and carbon dioxide (CO2). The presence of corrosion damage, which is characterized by local material dissolution and pitting formation under the influence of CO2 and/or H2S, provides the initiation sites in a fatigue cracking mechanism. The fatigue crack propagation in corrosion aggressive environments is associated with the following factors: (1) local tensile stress concentration at crack tip, and (2) local corrosion dissolution. Therefore, using a material that tends to re-passivate as it interacts with the environment would be the optimum solution in order to mitigate the likelihood of field failures and reduce overall operating costs. Regarding passive film disruption processes abrasion and high temperature influences were not considered at this stage of the present study and repassivation kinetics were not measured. Conventional sucker rod production processes include normalize and temper (N&T) or quench and temper (Q&T) heat treatments to meet desired strength levels of low alloy steels. In order to enhance the corrosion properties and provide a resistant sucker rod solution, 13Cr martensitic stainless steel may provide a viable alternative to low alloys steels. This paper focuses on the characterization of 13Cr sucker rod material by comparing the general corrosion and corrosion fatigue performance with low-alloy steels.