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This paper documents the basic SCC and corrosion rate behavior of a new 150 ksi yield strength TS temper in Levels I, II, IV, V and VII environments. Microstructural observations, corrosion rate and resistance to SCC in full immersion proof ring static tensile tests are reported.
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Results of the stress corrosion cracking tests showed that wrought UNS S31803 was not resistant to environmentally-induced cracking or corrosion in the test environment. A difference in surface finish did not have a significant effect.
This paper provides an overview of the existing literature with regards to the understanding of cracking in molybdenum-containing 13Cr alloys and provides suggested paths of investigation.
HFW pipes is considered a cost-effective pipe option for oil and gas pipeline projects. The HFW seam performance is always a concern, especially in challenging environments such as low temperature applications and wet sour services. One of the challenges include the seam properties to resist sulfide stress cracking (SSC) or hydrogen embrittlement (HE) when exposed to hydrogen charging environment such as a wet sour service.
This paper details challenges of high pressure sour gas projects with high salinity and provides cases of field history, explanation regarding material selection framework and technical challenges during the design, execution and operating phases of sour service projects.
This paper addresses the challenges to provide example of engineering solutions through the use of corrosion resistant alloys and non metallic materials to maintain the integrity of flowlines and process equipment in severe sour service.
Top-of-the-line corrosion (TLC) of carbon steel (CS) pipelines can be encountered during the transportation of wet gas under stratified flow conditions where temperature differences between the internal and external environments results in condensation of saturated vapors and water-wetted surface on the upper portion of the inside pipeline surface causing corrosion issues.1 Initially at least, the condensed water phase can be particularly corrosive with a low pH caused by dissolved acid gases (such as carbon dioxide and hydrogen sulfide) as well as organic acids in an unbuffered thin water film. Like bottom-of-the-line corrosion, TLC can be dominated by either carbon dioxide or hydrogen sulfide corrosion mechanisms.
Sour corrosion and iron sulphide scale deposition are two common flow assurance issues encountered in oilfields. Sour oil wells typically produce crude along with produced water and a significant amount of acidic gases such as carbon dioxide and hydrogen sulfide. The high pressure and temperature conditions under the downhole tend to cause severe corrosion damage including metal loss and pitting, along with iron sulphide scale deposition. Iron sulfide deposition in sour wells is a corrosion induced scale problem. It potentially causes production decline, restricted well intervention, well shutdown, or even severe consequences towards to the abandoned wells.
Mitigating oil and gas production with chemical inhibitors is challenging when high temperature (>120°C) and H2S is present. The high temperatures associated with deep wells and thermal recovery methods demand an advancement in conventional inhibitor technologies. Traditional organic inhibitors struggle to protect carbon steel assets lending them susceptible to localized corrosion in sour environments. These environments require inhibitors with a combined thermal stability and persistency to provide uniform filming and corrosion protection.
For high temperature corrosion applications imidazoline chemistry ranks highly as a chemistry likely to be able to mitigate corrosion at elevated temperatures. However, at temperatures between 120 and 150°C performance is very system specific while over 150°C performance can be severely limited. An extensive in-house screening program was undertaken which identified a generic chemistry (pyrimidine) that exhibited the required performance characteristics up to 175°C for a variety of field applications. Based on this work, several other materials exhibited performance benefits for alternate applications, for instance high temperature, deep water applications. Laboratory testing of the novel corrosion inhibitors at high temperatures, also highlighted the limitations of corrosion test methodologies for evaluating inhibitors under extreme conditions.