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Repeated cyclic potentiodynamic polarization (CPP) measurements were performed in different environments for both carbon steel and Type 304L stainless steel. The effect of different environmental species, nitrite and hydroxide on repassivation/reactivation mechanism of carbon steel is examined.
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Laboratory investigation performed to evaluate the impact of key Hanford tank waste chemical constituents on corrosion of Type 304L stainless steel (UNS S30403), which is the material of construction for the site’s evaporator.
The Effluent Treatment Facility (ETF) at the Hanford nuclear-waste storage facility is a waste treatmentfacility permitted under the Resource Conservation and Recovery Act of 1976 (RCRA). The facility removes radioactive and hazardous contaminants from various sources such as condensate wastewatergenerated by 242-A Evaporator campaigns, groundwater projects, solid waste disposal facilities, andother Hanford clean-up activities. The waste processed by the ETF is substantially more dilute than thewaste stored in the tanks.
The Hanford Site stores over 50 million gallons (190 million liters) of legacy nuclear process waste that was generated from plutonium separations and waste management processes. This waste, in the form of supernatant liquids, saltcakes, and sludges is contained in large underground storage tanks, up to a million gallons (3.78 million liters) in capacity and lined with carbon steel. The waste was made highly alkaline to ensure passivation of the carbon steel, but it also contains nitrate, in high concentrations, along with fluoride and chloride that poses risks for stress corrosion cracking and pitting corrosion.
The Hanford Nuclear Reservation contains radioactive and chemically hazardous wastes arising mostly from weapons production, beginning with World War II and continuing through the Cold War. The wastes are stored in 177 carbon steel underground storage tanks, of which 149 are single-shell tanks (SSTs) and the remaining are double-shell tanks (DSTs). The U.S. Department of Energy, Office of River Protection is responsible for retrieving the tank wastes, treating them in order to encapsulate them in glass logs, and then permanently closing the tanks and associated facilities.