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Corrosion under thermal insulations namely CUI (Corrosion under insulation) is a key degradation process in hydrocarbon facilities which poses asset integrity risks. 1 CUI is reported as the reason behind 40-60% of failures of the process piping in a typical oil refining facility. Speaking smaller-sized process piping (i.e., NPS < 4”), up to 81% of reported failures are known to result from CUI. 2 Monetary spending to inspect and fix CUI-related failures cost 10% of overall maintenance budget in a typical medium-sized oil refinery. 2 CUI risk is influenced by numerous operational and environmental factors which impedes its management in a typical AIM (Asset integrity management) program. The
To support installed tube lines, plastic clamp systems (which cause a high risk of corrosion failure of the pipe and tube) have been widely used. Crevice corrosion resistance of such was investigated based on the standard test methods. Characteristics were analyzed and operational life time estimated.
Corrosion failures in the oil and gas industry are dominated by localized failures in carbon steel; however, the industry has yet to develop standards for localized corrosion specifically for low alloy carbon steels (CS) such as UNS K03014 (API) 5LX65 [X65]) or UNS G10180 (C1018). The reasons for the lack of standardization are understandable as they are not trivial. The challenges are as follows: 1) CS pitting is more complex than pitting on stainless steels (SS) and can be impacted by corrosion byproducts and other forms of scales, and 2) surface finish of a test coupon or electrode has a significant impact on the three phases of pitting: initiation, propagation, and termination.
The storage and transportation of biofuels continue to be of interest. Material compatibility issues arise. For alcohol fuels, stress corrosion cracking of steels, and swelling and leaching of various polymeric materials. This paper will provide an overview of research that has been conducted in alcohol fuels.
Cases illustrating the capability of the multi-electrode array in detecting the initiation and propagation of localized corrosion and coating failure: (i) Monitoring localized corrosion…(ii) Visualizing passivity, its breakdown…(iii) Imagining coating disbondment under overprotection.
In previous years, we have explored the use of electrochemical sensors for humidity and corrosion measurements inside of natural gas pipelines. Designed to operate in systems where a conductive aqueous phase is intermittent or unavailable, these membrane-based sensors utilize electrochemical techniques such as linear polarization resistance and electrochemical impedance spectroscopy to determine the environment’s corrosivity to the pipeline material. We now aim to explore this sensor’s performance and capabilities in more complex systems, specifically in environments that promote localized corrosion. Using the aforementioned electrochemical techniques, along with electrochemical noise and cyclic voltammetry, we probe and monitor localized corrosion and general corrosion of X65 steel in the presence of inorganic pitting agents. Experiments are conducted in both aqueous and nonaqueous environments. The additional functionality increases the quantity and quality of corrosion data from these sensors, offering to internal corrosion-monitoring programs a more complete picture of real-time corrosion within their natural gas pipelines.
Transportation of energy carriers (not only oil & gas, but also hydrogen, ammonia, methanol, heating fluids) and carbon dioxide requires the use of extensive pipeline networks that are usually built in metallic materials which are subject to material degradation. Carbon steel being the most prevalent due to its properties, availability, cost, and references. Carbon steel as well as other metallic materials suffer from corrosion processes.
Recently, the nickel-based alloy UNS N08827, commercially known as VDM ® Alloy 825 CTP(3), has been presented to the oil and gas industry as an alloy that has been developed to fill in the existing gap between both UNS N08825 and UNS N06625 in terms of localized corrosion resistance. It is a solid-solution nickel alloy with chemical composition similar to UNS N08825, except for its doubled molybdenum content and the no addition of titanium.
Materials qualification testing of corrosion resistant alloys (CRAs) typically involves the use of simple pass/fail tests. Modification of existing standards is recommended for environments in which pit initiation is statistically improbable but pit propagation is rapid, e.g. low chloride/high H2S.