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Development of new oil and gas fields is likely to involve sour reserves to an increasing degree. Sourproduction often brings about difficulties in terms of asset integrity, related particularly to corrosionmitigation. Employing corrosion resistant alloys implies a considerable escalation in investment costs. On this basis the use of carbon steel and CO2/H2S corrosion inhibition remains a highly desirableoption.
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Sour corrosion and iron sulphide scale deposition are two common flow assurance issues encountered in oilfields. Sour oil wells typically produce crude along with produced water and a significant amount of acidic gases such as carbon dioxide and hydrogen sulfide. The high pressure and temperature conditions under the downhole tend to cause severe corrosion damage including metal loss and pitting, along with iron sulphide scale deposition. Iron sulfide deposition in sour wells is a corrosion induced scale problem. It potentially causes production decline, restricted well intervention, well shutdown, or even severe consequences towards to the abandoned wells.
An experimental study of corrosion of carbon steel in the presence of H2S, CO2 and acetic acid has been carried out. H2S and CO2 partial pressures up to 10 bar each were applied, with temperatures of 25 and 90oC.
Carbon steels such as API 5L X65 are widely used oil and gas exploration, production and transportation service. However, these steels tend to corrode in the presence of wet CO2 and corrosion is more pronounced in the presence of dissolved salts and acids. Other metals, alloys and polymers also degrade in the presence of high pressure gaseous and supercritical CO2. The corrosion rate of carbon steels in some aqueous environments have been reported to be more than a few millimeters per year.9-10 The situation could be further exacerbated by H2S where cracking can be an issue for high strength steels.
In sour (H2S) corrosion systems, a small amount of H2S can retard the general CO2 corrosion rate of carbon steel by forming a passive iron sulfide (FeS) layer [1], [2]. Environmental factors dictate the formation of protective or partially protective FeS layers on carbon steel surfaces. High H2S levels often result in stable films that reduce the corrosion rate, contingent upon the maintenance of the sulfide layer [2]. Conversely, in slightly sour systems, which initially form mackinawite (FeS) [3], the system has the potential to cause pitting and extremely high localized corrosion rates [2].
Corrosion and corrosion inhibitor qualification testing has been the subject of many publications over the years, with various guidelines and in-house protocols produced. This has led to a rather large set of test approaches for the qualification of corrosion inhibitors (CIs) for application in oil and gas production facilities.
For challenging conditions, including severe downhole conditions, final testing is often performed via specialized autoclaves or high-pressure flow loops to allow tests to be conducted under conditions as close to those pertaining in the field: T, P, pCO2 and pH2S (or more realistically, fugacity of CO2 and H2S), and as close as can be achieved to the field hydrodynamics.
Extremely corrosive environments of today’s oil and gas exploration requires more expensive Corrosion Resistant Alloys (CRAs) to be used for equipment such as tubulars. Material selection for oil and gas wells, especially those containing high hydrogen sulfide (H2S) and carbon dioxide (CO2) partial pressure, is very crucial. Hydrogen sulfide and carbon dioxide are quite aggressive to the materials used in oil field environments. The material of choice for these oil wells has to be reliable and cost-effective. This makes the material selection process a very complex and difficult task involving both financial and safety risks analysis.
In order to implement an effective iron scale mitigation strategy, operators first need to identify the main source of iron in the system. This work describes a method to predict the “maximum dissolved iron” (MDI) concentration in a reservoir/production system.