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Previously, precipitation of SI and Ca2+ was investigated. Similar work has also been performed by other researchers. The current paper presents corresponding experimental results where the binding of divalent cations Ca2+ and Sr2+ to 9 phosphonate SIs at pH 8.5, 95oC is investigated.
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How different families of scale inhibitors impact corrosion inhibitors performance in the presence of each other. Fundamental properties of both chemistries and how their interaction can be understood at the molecular level.
Scale and corrosion inhibitors are commonly used in many oil and gas production systems to prevent inorganic deposition and to protect asset integrity. Scale inhibitor products are based on organic compounds with phosphate or carboxylic functional groups such as amino phosphonates, phosphate esters, phosphino polymers, polycarboxylate and polysulfonates,1 as shown in Figure 1. These anionic groups have strong affinity to alkaline earth cations and can adsorb on the active growth sites of scale crystal (Figure 2), resulting in stopping or delaying the scale formation process.
Metal-carbonate scales are a double-edged sword for upstream oil and gas production engineering. On one hand, many of these scales can lead to serious setbacks if untreated, such as production interruption. One common example is calcite scale deposition on production tubing.
This production asset located in the deep-water offshore Brazil, producing heavy oil in the range of 16 to 24 oAPI. Mudline caisson separators with electrical submersible pumps (ESPs) are used to process fluids from multiple wells and boost them to the receiving floating production, storage, and offloading (FPSO) vessel(1). There are significant flow-assurance and corrosion challenges in operating the asset. One of the challenges is the production fields have limited subsea umbilical, necessitate the use ofmultifunctional products to maintain the field’s integrity and mitigate any flow assurance and scale issues.
F22 is a low alloy steel that typically contains 12% Carbon, 2.25% Chromium, and 1.0% Molybdenum1. This steel has been widely used in oil production systems, especially in well head design and construction. As a low alloy steel, F22 can be corroded by oilfield chemicals under certain circumstances. For example, it was observed in the Gulf of Mexico that typical scale inhibitor chemistries caused severe corrosion on F22.
Mineral scale deposition is one of the major flow assurance issues for the oil and gas industry. When an oil or gas well produces water, there is the possibility that scale could form either by the mixing of incompatible waters forming oversaturated brine or by direct precipitation of the water that occurs naturally in reservoirs due to the changes in pressure, temperature, or pH. Scale inhibitors are commonly used to prevent mineral scale formation during oil and gas production and mitigate this flow assurance issue.
The formation of mineral scales is one of the most problematic threats to the oil and gas operations which can lead to loss of production, increased lifting costs and assets deterioration.1 Mineral scales can precipitate at any locations within an oil and gas production system and create blockage in perforations, production tubulars, pumps, and surface equipment. The formation of scale deposits can be attributed to the mixing of incompatible waters from different production zones or physical and chemical condition changes associated with produced water transporting from reservoir to wellhead and further to processing facilities.
Seawater injection is commonly utilized for offshore wells to maintain or increase oil production; however, treatment for seawater before injection is always necessary to reduce or remove bacteria, dissolved oxygen, sulfate, and other impurities. Seawater typically has >2000 mg/L sulfate. Without proper sulfate removal, such high levels of sulfate can cause not only barium sulfate, strontium sulfate, and calcium sulfate scales, but also reservoir souring and H2S corrosion in the presence of sulfate reducing bacteria (SRB). Therefore, sulfate removal from seawater is critical before seawater injection into reservoir.