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Picture for ASH Testing to Confirm Mix Ratio by Volume of Plural Component Applied Material
Available for download

ASH Testing to Confirm Mix Ratio by Volume of Plural Component Applied Material

Product Number: 51324-21133-SG
Author: Steve Liebhart
Publication Date: 2024
$40.00
Epoxy pipe coatings are often used for coating the exterior of buried pipe for means of corrosion protection and other robust performance characteristics they provide. One class of coatings often used for this service are two-component fast curing epoxy products applied using plural component application equipment. With this type of equipment, both paint components are heated and metered separately, until pumped through a static mixer(s) for mixing just prior to being sprayed. What assurance does an applicator have that their equipment is metering and mixing the materials properly? And how can it be determined with accuracy to provide confidence that the material will perform as advertised? After all, good lab practices ensure that the performance properties of the product were evaluated on correctly metered and mixed materials in a lab. There are a handful of quality control tests that can be performed on field applied coatings, but they are most-all a bit crude and only give you a general idea that the coating looks to be on ratio. Depending on the materials being used and how they are formulated, a more sophisticated approach to evaluate the accuracy of the mixed material is to perform ash testing on cured samples prepared prior to or at the same time as material being applied for service. The ash content value of the mixed/cured material can be used to calculate and verify that the required stoichiometric ratio by volume of the two-component mix was achieved. Having a high degree of confidence that the protective coating applied to the pipe was mixed correctly should provide increased confidence it will perform correctly and do its part in preserving the integrity of the pipeline.
	Picture for Assessing Susceptibility of Insulation Materials to IGSCC under Hot and Wet Conditions: A Novel Test Method
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Assessing Susceptibility of Insulation Materials to IGSCC under Hot and Wet Conditions: A Novel Test Method

Product Number: 51324-20920-SG
Author: Yuan Li; Lisa Sopkow; Simon Yuen; Matthew Krantz; Tony Lam
Publication Date: 2024
$40.00
Picture for Assessment of Ammonium Chloride Corrosion in Refinery Crude Distillation Unit Overhead Conditions
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Assessment of Ammonium Chloride Corrosion in Refinery Crude Distillation Unit Overhead Conditions

Product Number: 51324-21131-SG
Author: H. Li; Y. Yoon; Russell D. Kane
Publication Date: 2024
$40.00
The corrosion in crude unit overhead systems, specifically related to acidic attack and under-deposit corrosion caused by salt formation, has been extensively documented in both industry and literature. However, the absence of comprehensive corrosion data correlating critical environmental and flow variables has posed challenges in evaluating corrosion and selecting appropriate materials. To address this issue, a Joint Industry Program (JIP) was conducted with the primary objective of generating engineering data on the corrosion behavior of commonly used construction materials in atmospheric overhead systems of refinery crude distillation units (CDU-OH). The study focused on investigating the effects of HCl, NH3, NH4Cl, H2O, and H2S in the presence of ammonium chloride, aiming to identify key parameters associated with three prevalent forms of corrosion: under-deposit, water dew point, and aqueous corrosion. Through meticulous thermodynamic modeling and corrosion evaluations performed in simulated environments that accurately represented relevant conditions, the impact of these key parameters on the corrosion of six frequently used materials of construction—namely, carbon steel, 410 stainless steel, Alloy 400, Titanium, Alloy 625, and Alloy C-276—was rigorously evaluated. The corrosion rates of these materials under various test conditions were quantified, leading to the development of a corrosion prediction model. This model serves as a valuable tool for determining conditions for ammonium chloride-induced corrosion in CDU-OH systems, aiding in the assessment and decision-making processes pertaining to material selection.