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The authors have developed and introduced a molecular mechanistic model that quantifies and predicts simultaneous naphthenic acid and sulfidation (SNAPS) corrosion rates. This was subsequently presented as a definitive mechanistic corrosion prediction framework describing the molecular basis of the model’s reactions, kinetics, and mass transport of reactive organic sulfur compounds (ROSC) to vessel walls . In this molecular model, sulfidation corrosion is calculated for direct heterolytic reaction of ROSC with solid surfaces. As recently reported, % total S and ppm mercaptans are used as input for the ROSC reactions in the model (Figure 1).
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