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Knowledge of the localized corrosion environment on a metal substrate can provide the critical link between atmospheric data and corrosion morphology and can enable the formation of a framework to predict service life as a function of environment. Over the last few decades the analytical characterization of bare metal surfaces undergoing atmospheric corrosion has improved, resulting in a more complete understanding and consideration of the environmental parameters involved. However, the corrosion processes and the role that the environmental parameters play in what is a multiphase system is rather complex involving chemical reactions and equilibria, ionic transport phenomena, and gaseous, aqueous and solid phases.
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