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Encapsulation of Linseed Oil & Tung Oil in urea-formaldehyde shells was performed using in-situ polymerization technique. Thin film self-healing coatings with uniform and quick self-healing ability were achieved with microcapsules at concentration of 3 wt%. Anti-corrosive performance was evaluated using immersion test & electrochemical impedance spectroscopy (EIS).
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Self-healing coatings have been promising due to their automatic recovering functions, which can extend the coating lifetime with lower maintenance costs. One of the most effective strategies to achieve self-healing property is to encapsulate healing agents inside microcapsules and integrate the microcapsules into the coating matrix.
Natural gas pipelines are subject to internal corrosion. Internal corrosion of steel pipelines can cause natural gas leakage, leading to wasted energy, explosion hazards, and methane emissions. The U.S. Department of Transport reported numerous case histories of corrosion problems and failures in wet gas pipelines. The National Energy Technology Laboratory (NETL) performed an incident survey from 2010 through 2018 and found that 112 (12%) of these incidents in the U.S. transmission lines were caused by internal corrosion.
Self-healing polymers are a new class of smart materials, which have the capability to autonomically repair themselves after damage, without the need for detection or repair by manual intervention. To expand the scope of practical applications, new self-healing chemistries have been developed and evaluated for use in a wide variety of applications including coatings.
Low-viscosity oils could potentially act as self-healing barrier coatings because they can readily flow and reconnect to heal minor damage. For the same reason, however, they typically do not form stable coatings on metal surfaces. Increasing viscosity helps to stabilize the oil coating, but it also slows down the healing process. Here, we report a strategy for creating highly stable oil coatings on metal surfaces without sacrificing their remarkable self-healing properties.
Truly self-healing materials have the capability to repair themselves when they are damaged without the need for any external intervention. Self-healing systems based on microencapsulated healing agents developed by researchers at the University of Illinois at Urbana-Champaign were initially developed with polymerized resins and reinforced polymer composites as the intended applications. In this paper, we discuss the principles that emerged in the design of these self-healing systems and how they are presently used in design and optimization of self-healing systems for industrial and marine protective coatings.