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This paper reports liquid metal embrittlement (LME) test results for a variety of common oilfield and processing plant alloys exposed to liquid mercuryp across a range of temperatures. Test methods used include slow strain rate testing and C-ring tests.
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The bulk characteristics of Chemically Bonded Phosphate Ceramic (CBPC) coating was investigated for marine bridge application in alternate wet and dry exposure. Assessment of possible bulk coating degradation was made by physical testing, Mercury Intrusion Porosimetry (MIP) and electrochemical techniques. The bulk coating material was observed to become chalky and in some cases form cracks when exposed to alternate wet and dry conditions. Cohesive strength appeared to degrade.
Liquid Metal Embrittlement (LME) phenomenon occurs when the certain molten metals wet the specific alloys, causing drastic ductility reduction that normally is associated with the formation of an intergranular crack that is sudden and brittle in nature. High tensile stress is also known to promote cracking; however, cracks may develop merely by contacting molten metal with a susceptible alloy as there is only a small amount of low-melting-point metal required to cause LME.
Results of exposing UNS R56404 forging and pipe product forms to liquid mercury over the 25°-232°C range while highly stressed at & beyond the alloy’s yield point via three loading modes are reported. Included are: sustained load 90 day C-ring tests, slow strain rate tensile testing, and rippled slow strain rate cyclic tensile loading.
Liquid metal embrittlement (LME) involves penetration of a liquid metal into a solid metal that leads to brittle fracture. A test program was established to evaluate the susceptibility of various metallic materials to LME by mercury.
In oil and gas production, corrosion is a major cause of failures. These failures result in significant environmental contaminants, safety problems, increase in the high operating costs and decrease in the production rates. Extensive literature is available about various corrosion drivers and their mechanisms, helping operators to avoid or mitigate these catastrophic failures.
The objective of the study is to evaluate the effect of elemental and ionic Hg towards carbon steel corrosion in sweet and sour environments with and without Corrosion Inhibitor (CI) injection. Several evaluations are conducted to study the effect of Hg deposition and fluid corrosion behaviour via Corrosion Rate (CR), solution chemical properties, surface profile and corrosion product analysis. Bubble test was carried out in glass cells and high-pressure rotating cylinder electrode (HPRCE) autoclaves test under multiple variables to study the CR behaviour.