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Picture for Predicting Corrosion of Successive Feeds in Distilling Units - An Experimental Approach
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Predicting Corrosion of Successive Feeds in Distilling Units - An Experimental Approach

Product Number: 51324-20668-SG
Author: Gheorghe Bota; Ishan Patel; Peng Jin; David Young
Publication Date: 2024
$40.00
Cheap heavy crudes become attractive for oil refineries to increase their benefit margins but the corrosivity of heavy crudes compels the refinery engineers to blend them with the more expensive light sweet crudes. Crude oil blends with complex composition including organo-sulfur compounds, fatty acids, nitrogen and chlorine compounds become corrosive when processed at high temperatures due to these reactive species. Therefore, maintaining corrosion control is a constant effort in oil refineries, and it involves the use of dedicated corrosion models combined with specific experimental lab procedures and methods. This work is presenting the practical application of a lab testing procedure used for predicting the high temperature corrosivity of different crude fractions that were run successively for different time periods in a specific “flow-through” apparatus. The testing procedure consists of two distinct phases performed in the same apparatus, at the same temperature, and for different time durations. During the first phase of the test, scales are formed using a distilling fraction on metal samples and further, in the second test phase, these preformed scales on samples are exposed without interruption to a different distilling fraction. Thus, the two successive test phases, each using a different distilling fraction, are associated with the “changing feeds” in the distilling tower. Corrosive effects are evaluated by sample weight loss measured in successive fraction tests and in separate tests performed with each of the selected fractions. Experimental results are compared to predictions of a corrosion model for sulfidation and naphthenic acid corrosion.