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Crude unit overhead systems contain complex mixtures of hydrocarbon water and various ionic species. Ionic modeling has been used to better understand the rapidly changing phase behavior in this system and to shed some light on some factors which may influence corrosion.
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In recent years, unexpected failure caused by sulfidation corrosion have increased presumably because many refineries diversify the crude oils to process them. Crude oils contain corrosive species such as sulfides, nitrides, chlorides, organic acids and chemical additives. In these corrosive species, sulfides in the fluids cause sulfidation corrosion operating at temperature above approximately 260 °C1.
Written for Plant Operators, Process Engineers, Metallurgists, Maintenance Engineers, Inspectors, and all others who deal with crude unit corrosion and fouling. Based on industrial experience and reflects Industry’s consensus 2016 NACE, API
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Written for Plant Operators, Process Engineers, Metallurgists, Maintenance Engineers, Inspectors, and all others who deal with crude unit corrosion and fouling. Based on industrial experience and reflects Industry’s consensus. 3rd edition 2016 NACE, API.
Thermal and/or hydrolytic stability behavior of solutions of carboxylic acids. This work thermally stressed aqueous solutions of carboxylic acids and analyzed the resulting solution and headspace. Expected corrosion impact on distillation overheads and brine rundown systems.
HISTORICAL DOCUMENT. Corrosion mechanisms in refinery crude distillation unit (CDU) distillation tower overhead systems and current industry practices for mitigating or controlling this corrosion.
There is evidence of significant physical fouling of crude units from polymerization of MEA triazine scavenger in the presence of hydrogen sulfide. This paper highlights this new impact.