A metallographic examination was conducted on a set of degraded alloy thermowells,
which were installed in the fluidized bed of a coastal fluidized bed biomass (waste-wood)
power boiler. Because of the importance of temperature measurement in the boiler control
strategy, the plant wanted to understand the corrosion mechanism and choose longer-lived
materials. The analytical results suggest that the corrosion was caused by contact with a
molten chloride-containing salt. The relative corrosion resistance ranking order of Alloy 600 >
Alloy 625 > Type 310H stainless steel > Type 446 stainless steel is consistent with the
reported influence of nickel and chromium alloying on corrosion resistance in molten chloridecontaining
salts.
Keywords: power boilers, biomass, fluidized bed, thermowells, corrosion, molten salt, chloride,
sulphate, alloy