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Picture for Effect of the Superduplex Microstructure on the Hydrogen Embrittlement Susceptibility
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Effect of the Superduplex Microstructure on the Hydrogen Embrittlement Susceptibility

Product Number: 51319-13062-SG
Author: Pauline Huguenin
Publication Date: 2019
$20.00

Superduplex stainless steel UNS S32750 / EN 1.4410 presents very high corrosion resistance together with elevated mechanical strength making it especially suited for subsea systems. Despite the material excellent properties a number of in-service failures have been recorded especially when it is subjected to cathodic protection. This grade is also known to be sensitive to intermetallic phase precipitation e.g. σ-phase whose deleterious effect is well documented. Therefore manufacturers have optimized metallurgical routes to deliver superduplex products free from intermetallic phases. However very few residual particles may be present under the form of centerline intermetallic stringers and their effect on hydrogen embrittlement is not well documented.The present study aims at evaluating the influence of the intermetallic phases in centerline stringers on the hydrogen embrittlement susceptibility of superduplex stainless steel. Heat treatment have been performed on superduplex sheets in order to obtain different configurations of intermetallic phase – free from σ-phase presence of centerline intermetallic stringers presence of σ-phase over the full thickness. Specimens have been then tested by means of slow strain rate tensile test in simulated deep sea water (0.5 M NaCl 4 °C) under cathodic polarization at -1100 mV/SCE. All duplex microstructures and fracture surfaces were investigated using low and high magnification microscopy. The strain to fracture is estimated by the section reduction at the fracture surface and the hydrogen embrittlement susceptibility is defined for each microstructure as the reduction of the strain to fracture compared to a reference test in deionized water at 4 °C (RAR).With the presence of hydrogen fracture mode changes from ductile to transgranular quasi-cleavage. No effect of centerline intermetallic stringers (up to 0.08% of sigma σ-phase) on hydrogen embrittlement susceptibility has been measured.Considering the sample with σ-phase over the full thickness the resistance to hydrogen embrittlement is artificially high due to the low initial ductility measured in the reference test. Therefore the influence of hydrogen was only insignificant as observed on the fracture surface which remains ductile.

Picture for Enabling Decarbonization through Conversion of Natural Gas Pipelines to Blended Hydrogen Service through a Nanocomposite Surface Treatment
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Enabling Decarbonization through Conversion of Natural Gas Pipelines to Blended Hydrogen Service through a Nanocomposite Surface Treatment

Product Number: 51324-21204-SG
Author: Ganesh Kumar Arumugam; Sumil Thapa; Venkat Kamavaram; Andrea Mansfeld; Ramiro Maldonado
Publication Date: 2024
$40.00
The next phase of a global energy transition is hinging closely on finding fuel sources with substantially reduced carbon footprint. One way of doing so is to enable the use of Hydrogen (H2) rather than natural gas while still maintaining the existing legacy transport pipeline infrastructure. The presence of hydrogen in natural gas blend has been shown to cause weakening of steel even at extremely low concentrations and steps must be taken to mitigate the presence of hydrogen. Although embrittlement can be mitigated using specific metal alloys, the extensive cost of such retrofitting (up to $4.7M per mile) has made this economically unfeasible. One option that could substantially reduce this cost by as much as 90% is the use of new liners or barrier materials to limit the ability of hydrogen to diffuse into the steel. One such material coating that claims a unique combination of a “low-surface energy,” chemical- and abrasion-resistant topcoat material combined with a highly gas-impermeable and corrosion-resistant but physically fragile base layer is evaluated in this paper. This composite structure allows for the material to have sufficient mechanical strength to be field deployable in a typical pipeline environment. This work describes the establishment and use of a new experimental laboratory setup designed to test the effect of a nanocomposite material deposited onto legacy steel grades such as X52 and X70. The high-pressure, high-temperature mechanical testing bed could simulate all environmental conditions that a future pipeline would face hydrogen/methane blends anywhere from 0 – 100% temperature exceeding 200°C and pressures between up to 2000psi. Facilities capable of safely and controllably testing how metals react in the presence of hydrogen fuel blends will be essential to the industry as the demand for establishing new standards for hydrogen energy transport grows. This case study demonstrates how one might go about designing and testing a novel coating or surface treatment material, and will discuss whether such coatings are viable solutions, and where improvements need to be made.
Picture for Full-Scale Testing Validation and Quantification of Optimized Engineered Composite Repair Systems for Pipeline Repair
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Full-Scale Testing Validation and Quantification of Optimized Engineered Composite Repair Systems for Pipeline Repair

Product Number: 51319-13439-SG
Author: Matt Green
Publication Date: 2019
$20.00

For almost three decades composite repair technology has provided valuable alternatives to operating companies in maintaining the integrity of their high-pressure gas and liquid pipeline systems. Early adopters of the technology helped to push the usage of these beneficial materials to where they are today. As with all technology increased usage drives increased scope of usage and there have been extensive and comprehensive full-scale testing programs dedicated to pushing the boundaries and opening new defect repair options. These have been funded jointly by industry and manufacturers and have yielded successful results further showcasing the full range of benefits that composite materials can provide. Benefitting from this history and background allows for a better repair option based on experience and lessons learned. Development of new technologies methods and materials has been ongoing and results show improvements may be made by using lessons learned in conjunction with technologies now available.The contents of this paper focus and provide details on the development of specialized composite technologies for reinforcing anomalies such as corrosion and dents subjected to aggressive operating conditions. Additionally small-scale coupon-level testing results are used to characterize the effects of constitutive component changes in order to take the next steps prior to full-scaling including burst and cyclic pressure testing. Information is included on the initial design process used by engineers to optimize reinforcements using constitutive properties and insights from previous testing and research programs to guide the advancements in the understanding of the materials. Detailed test results and industry comparisons are included with information on how both coupon-level and full-scale test results can be used to assist operators in repairing and maintaining their pipeline systems using optimized composite reinforcing technologies.

Picture for Multiple Element Monitoring for Concrete Structures
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51315-5771-Multiple Element Monitoring for Concrete Structures

Product Number: 51315-5771-SG
ISBN: 5771 2015 CP
Author: Sean Brossia
Publication Date: 2015
$20.00
Picture for Assessment of Cement-Lined Pipelines and Challenges
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Assessment of Cement-Lined Pipelines and Challenges

Product Number: MPWT19-14342
Author: Murtada H. Alsalman, Itoro L. Akrasi, Zakariya H. Alyacoub
Publication Date: 2019
$0.00
Shanghai, China: Crossing the Cultural Divide
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Picture for 99612 THE OVER 20 YEAR OPERATING EXPERIENCE
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99612 THE OVER 20 YEAR OPERATING EXPERIENCE WITH CARBON STEEL TUBINGS AT ABU ATTIFEL FIELD. PROBLEMS AND SOLUTIONS

Product Number: 51300-99612-SG
ISBN: 99612 1999 CP
Author: Tiziana Cheldi, K. Rumash, Bruno Bazzoni
$20.00
Picture for 98305 APPLICATIONS OF LPR TO THIN FILM LIQUID
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98305 APPLICATIONS OF LPR TO THIN FILM LIQUID PHASES

Product Number: 51300-98305-SG
ISBN: 98305 1998 CP
Author: K. M. Lawson,M. Yunovich, D. L. Caudill
$20.00
Picture for Impact of Very Low Concentration of Soluble Salts on Coatings Performance
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Impact of Very Low Concentration of Soluble Salts on Coatings Performance

Product Number: 51319-13218-SG
Author: Andy Bodington
Publication Date: 2019
$20.00

For offshore platform maintenance coating operation dry grit blasting is a common practice to clean the steel surface. The offshore platform steels are in a various degree of corrosion. It is well known that dry grit blasting alone cannot remove salts completely and some residual salts remain on blasted steel surface. In offshore corrosive environment grit blasted steel surfaces will quickly become rusted within a couple of hours. It is hard to keep the desired near white metal finish for 2-4 hours until the coating spray application. There are several commercial cleaning chemicals to remove residual salts and to extend the surface cleanliness time.This paper covers the testing and comparison of some of these chemicals and impact on coating performance. The evaluation was in 2 parts:1. Compare various salt removal solutions.2. Evaluate the compatibility and impact of the best salt removal solution on coating performance.In the first part of the testing tests showed that one of the products did out-perform the other chemicals to remove residual salts and maintain a desired surface pH.The second part of testing was done since there was a concern about the compatibility of the salt removal product and coatings. Thus the best salt removal product was then further tested with various coating types applied. Three (3) atmosphere coatings and three (3) tank linings (immersion grade) were selected for the compatibility study.The conclusion was that one salt removal solution did out-perform other systems and the salt removal solution was compatibility with the various coatings and improved performance of the coating.

Picture for The API RP 14E Erosional Velocity Equation: Origin Application Misuse Limitation and Alternative
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The API RP 14E Erosional Velocity Equation: Origin Application Misuse Limitation and Alternative

Product Number: 51319-13206-SG
Author: Fazlollah Madani Sani
Publication Date: 2019
$20.00

Erosion of mild steel lines and equipment during the production of hydrocarbons from underground reservoirs is a complex and not fully quantitatively understood phenomenon becoming even more intricate when electrochemical corrosion is included. Oil and gas companies have always tried to account for this phenomenon with simple models. Over the last 40 years the American Petroleum Institute recommended practice 14E (API RP 14E) erosional velocity equation has been used by many operators to estimate safe production velocities in erosive-corrosive service. The widespread use of API RP 14E is a result of it being simple to apply and requiring little in the way of inputs. However there is very little scientific backing for this approach. The API RP 14E erosional velocity equation is often quoted to be overly conservative and to unjustifiably restrict the production rate or overestimate required pipe sizes.The present workprovides a review of literature on the origin of the API RP 14E erosional velocity equation its limitations misuses applications and known alternatives. This review suggests that a proper erosion model would provide a better description for the vast majority of conditions in oil and gas production systems to determine the safe operating velocity while maintaining a maximum production capacity and using cheaper materials or smaller diameter pipelines. However these models are more complex and are therefore not as widely applied. Overall there are currently no simple and readily available alternative formulae for calculating the erosional velocity and resort in many cases is a semi-empirical approach that includes operational experience.Keywords:erosion API RP 14E erosional velocity erosive-corrosive service operational experience

Picture for 96080 Material Selection for Wellhead Equipment
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96080 Material Selection for Wellhead Equipment Exposed to Chlorinated and Natural Seawater

Product Number: 51300-96080-SG
ISBN: 96080 1996 CP
Author: Stein Olsen, Manuel Maligas, Perry Nice, John Vicic, T. Vinn
$20.00
Picture for 99023 EFFECT OF BUFFER CAPACITY ON THE
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99023 EFFECT OF BUFFER CAPACITY ON THE CO2 PITTING OF STEEL

Product Number: 51300-99023-SG
ISBN: 99023 1999 CP
Author: Saadedine Tebbal, Norman Hackerman
$20.00
Picture for 97604 Corrsion Data Survey: The Next Generation
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97604 Corrsion Data Survey: The Next Generation

Product Number: 51300-97604-SG
ISBN: 97604 1997 CP
Author: Bijan Mashayekhi, Charles P. Sturrock, Carole D. Flanigan
$20.00
Picture for 01331 ZIRCONIUM MEETING THE CHALLENGES OF
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01331 ZIRCONIUM MEETING THE CHALLENGES OF THE NEW MILLENNIUM

Product Number: 51300-01331-SG
ISBN: 01331 2001 CP
Author: Te-Lin Yau,
$20.00
Picture for ASH Testing to Confirm Mix Ratio by Volume of Plural Component Applied Material
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ASH Testing to Confirm Mix Ratio by Volume of Plural Component Applied Material

Product Number: 51324-21133-SG
Author: Steve Liebhart
Publication Date: 2024
$40.00
Epoxy pipe coatings are often used for coating the exterior of buried pipe for means of corrosion protection and other robust performance characteristics they provide. One class of coatings often used for this service are two-component fast curing epoxy products applied using plural component application equipment. With this type of equipment, both paint components are heated and metered separately, until pumped through a static mixer(s) for mixing just prior to being sprayed. What assurance does an applicator have that their equipment is metering and mixing the materials properly? And how can it be determined with accuracy to provide confidence that the material will perform as advertised? After all, good lab practices ensure that the performance properties of the product were evaluated on correctly metered and mixed materials in a lab. There are a handful of quality control tests that can be performed on field applied coatings, but they are most-all a bit crude and only give you a general idea that the coating looks to be on ratio. Depending on the materials being used and how they are formulated, a more sophisticated approach to evaluate the accuracy of the mixed material is to perform ash testing on cured samples prepared prior to or at the same time as material being applied for service. The ash content value of the mixed/cured material can be used to calculate and verify that the required stoichiometric ratio by volume of the two-component mix was achieved. Having a high degree of confidence that the protective coating applied to the pipe was mixed correctly should provide increased confidence it will perform correctly and do its part in preserving the integrity of the pipeline.
Picture for 98490 ON SITE RUBBER LINING - APPLICATION OF
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98490 ON SITE RUBBER LINING - APPLICATION OF PRECURED AND SELF CURING RUBBER LININGS

Product Number: 51300-98490-SG
ISBN: 98490 1998 CP
Author: J. Fenner
$20.00