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Picture for Development of a New CRA Grade for High Pressure High Temperature Application
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Development of a New CRA Grade for High Pressure High Temperature Application

Product Number: 51319-12782-SG
Author: Cécile Millet
Publication Date: 2019
$20.00

In High Pressure High Temperature “HPHT” wells (pressure above 10000psi/690bar temperature above 300°F/150°C which contain CO2 (sweet corrosion) and H2S (sour service) the oil & gas operators need to select materials which are resistant in corrosive atmosphere during the well lifetime. At the same time high strength grades are usually required to meet collapse and burst properties. The aim of the end users is to get the specific grade which can resist to corrosion while minimizing the cost which involves qualification with corrosion tests.The API 5CRA standard defines corrosion resistant alloy (CRA) grades for casings and tubings from group 1 named “Super 13Cr 13-5-2” (suitable up to 356°F/180°C) to group 2 “Duplex” grades 22-5-3 (450°F/232°C) or “Super Duplex” 25-7-4 (482°F/250°C) and higher grades.Therefore when the well temperature is above 356°F/180°C duplex grades or higher are commonly selected as these materials have a larger application domain at higher temperature range.A new proprietary grade chemistry was developed to provide good corrosion performances up to 230°C 125ksi (862MPa) grade material and high impact toughness. From a metallurgical standpoint achieving targeted mechanical and corrosion performances has ended up in a multi-phases material (martensite delta ferrite and austenite). Most of the performances are mainly controlled by the phases balance which alloy optimization has enabled consistent control by heat treatment.Stress corrosion cracking performances were assessed and compared to Super 13Cr and Super Duplex materials showing significant benefice of chromium under high temperature. Potentiodynamic electrochemical measurements in H2S environment were performed at 24°C in order to evaluate pitting performance and assess risk of sulfide stress corrosion cracking confirming higher sulfide stress corrosion performance compared to S13Cr materials. X-ray Photoelectron Spectroscopy (XPS) characterizations provide deep knowledge about it passive film compositions underlining the beneficial effect of high chromium within the grade.This solution offers to Oil and Gas operators a cost effective designed seamless tubes for high temperature well reservoir condition as alternative to duplex materials.

Picture for Destructive Examination Protocol for 3013-Container-Package Storing Plutonium-Bearing Materials
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Destructive Examination Protocol for 3013-Container-Package Storing Plutonium-Bearing Materials

Product Number: 51324-20811-SG
Author: Roderick E. Fuentes; Michael J. Martínez-Rodríguez; Elizabeth J. Kelly
Publication Date: 2024
$40.00
The 3013-container-package consists of a convenience, inner and outer container and is used for long-term storage of plutonium-bearing materials. A destructive examination (DE) protocol has been developed to examine the container package visually and with microscopic aid to find any corrosion conditions that could result in the loss of the integrity of the container package over its lifetime. The DE protocol contains three main steps: initial container examination, helium (He) leak testing, and detailed imaging and analysis of the inner container closure weld region (ICCWR). The ICCWR has been determined to be bounding, defined as exhibiting worst case conditions for stress corrosion cracking (SCC) of the inner container. To assess SCC in the ICCWR, the inner container lid is cut into quarters and the weld and He-leak testing gasket are removed. Then a citric acid wash is performed to remove adherent chlorides from the ICCWR. The wash is then sent for analysis to determine the concentration of chlorides in the ICCWR. While the analysis for chloride concentration is being performed, the quarter sections are further sectioned into 1/8th subsections by cutting each section in half. These subsections are washed using nitric acid to remove corrosion products. Then each subsection is imaged using a Wide Angle 3-D Measurement System (WAMS). After analysis of microscope images for potential SCC, additional imaging can be performed, including subsurface imaging. After review, a determination is made of whether the container integrity may potentially affect the safe storage of the material.
Picture for Conference Proceedings 2018- 11391 through 11719
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Conference Proceedings 2018- 11391 through 11719

Product Number: 51318-5
Author: Various
Publication Date: 2018
$0.00
Picture for Characterisation of a Novel Hybrid Anti-corrosive System Comprising Graphene Nano Platelets and Non- Metal-containing Anti-corrosive Pigments
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Characterisation of a Novel Hybrid Anti-corrosive System Comprising Graphene Nano Platelets and Non- Metal-containing Anti-corrosive Pigments

Product Number: 51319-13266-SG
Author: Andy Gent
Publication Date: 2019
$20.00
Picture for Development of High Strength grade and Cost Effective Super Martensitic Stainless Steel Solution for high CO2/H2S environment
Available for download

Development of High Strength grade and Cost Effective Super Martensitic Stainless Steel Solution for high CO2/H2S environment

Product Number: 51320-14715-SG
Author: Cécile Millet, Martien Deffo , Harold Evin, Guillaume Néel
Publication Date: 2020
$20.00

Practical Manual of Biocorrosion and Biofouling for the Industry, English Edition

Product Number: 38251
ISBN: 0952711591
Author: By Hector A. Videla
$30.00

Field Guide for Managing Iron Sulfide (Black Powder) within Pipelines or Processing Equipment”

Product Number: 37642-POD
ISBN: 978-1-57590-383-5
Author: Daniel E. Powell, Robert H. Winters, Mark A. Mercer
$190.00

This is a print-on-demand (POD) book that will be produced just for you in 2-5 days after your order. It should arrive at your door in about one to two weeks. However, due to supply chain and logistic challenges currently affecting the industry, it may take longer. Allow three weeks for international orders.

The Field Guide for Managing Iron Sulfide (Black Powder) within Pipelines or Processing Equipment offers practical guidance for corrosion control and operations personnel in managing black powder within their pipeline systems or processing equipment.

This book was written for new corrosion control professionals and operations personnel, who are based at production facilities. It provides straightforward, practical guidance regarding what is “black powder,” and why it may be a concern, field tests to be conducted, follow-up laboratory test that could be ordered, and an approach for using maintenance pigging, coupled with chemical treatments, to remove accumulations of “black powder.” 

It begins with a discussion of what is black powder and identifies health and safety considerations associated with H2S and the presence of black powder, identifying why there may be a concern. 

The Field Guide presents field and laboratory tests typically used to identify the presence of iron sulfide, and then discusses maintenance pigging and/or chemical treatments for removing such particulates. Several case studies are also presented. 

2019 NACE, 6 x 9" trim size, color, perfect bound, 264 pages

 

Field Guide for Managing Black Powder White Paper

 

Download the free white paper summary of this title to see specific areas of focus and discussion

Picture for The Effect of H2S Consumption on SSC Susceptibility of High Strength Wire Grades for Flexible Pipes
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The Effect of H2S Consumption on SSC Susceptibility of High Strength Wire Grades for Flexible Pipes

Product Number: 51319-13483-SG
Author: Merlin Bandeira
Publication Date: 2019
$20.00

Flexible pipes are widely used in offshore installations especially in Brazil to produce and export oil and gas. In order to guarantee safety operation in pre-salt fields without super estimate the field corrosiveness many efforts are dedicate to study the actual H2S concentration in the pipe annulus. The data presented in the literature point to a considerably lower H2S concentrations than those predicted based on traditional annulus permeation models. The consequences of these studies have direct impact on flexible pipes design suggesting the possibility to use lighter lower cost with good performance structures. However to specify correctly the armor wires is crucial to evaluate the corrosion resistance on annulus condition especially the stress corrosion cracking. The present study goal is to evaluate the corrosion performance of a range of flexible pipes armor wires considering susceptibility of SCC and HIC on laboratory simulated annulus condition. The laboratory tests were conceived to measure and compare pH H2S and Fe2+ concentration during the whole test period. The H2S flowrate was constant at 4 mL/min. All experiments were carried out at 30 oC 0.1 MPa using a gas mixture with 1% H2S in CO2. It was also controlled the ratio of liquid phase (synthetic seawater) and steel surface area (0.7 mL/cm2). The studied flow rate was 10-6 mL/min/cm2. A blank test without steel wires revealed that pH was stable at 4.9 and the maximal H2S concentration recorded was 20 ppm both after 150 h of test. On test simulating the annulus condition the pH was around 6.1 from 20 h of immersion until the end of the test (2000 h). The H2S concentration was always lower than 1 ppm and the Fe2+ concentration increased with immersion time up to 1200 ppm. Among the three high strength wire grades tested by four point bend test only one was susceptible to SCC under the conditions tested. Further studies will be presented concerning the HIC and microstructure influence on corrosion performance. The aim of this test program is to provide technical data to support future modifications on flexible pipe design with guarantee of good corrosion performance of armor wires.

Picture for Statistics to Compare Alloy 718 Properties from Additive Manufactured and Newer Mill-Produced Bar Stocks
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Statistics to Compare Alloy 718 Properties from Additive Manufactured and Newer Mill-Produced Bar Stocks

Product Number: 51319-12948-SG
Author: Manuel Marya
Publication Date: 2019
$20.00

Alloy 718 is a common oilfield material for permanent and service equipment in need of high-mechanical ratings and resistance to corrosion especially environmentally-assisted cracking in sour gas wells. In past decade Alloy 718 production from traditional and newer mills has greatly increased in response to global demands; independently yet driven by similar market growth additive manufacturing (AM) has expanded beyond rapid prototyping to become an industrial production process namely in the aerospace. Today 718 bar stocks as per API6CRA are produced by over a dozen mills worldwide;similarly 718 powder products are increasingly offered by both traditional and newer mills with intents to servea multitude ofAM technologies. Due to the rise of new economic forces in the O&G there are today needs for evaluating (ultimately qualifying) newer 718 producing mills as well as 718 powders in combination with various AM technologies. Due to concerns overraw-material properties a study was conducted to analyze 718 materials from these various origins utilizing (1) mill cert big-data analyses (2) third-party recertified mechanical test data (3) a multitude of sour service test results outside the traditional NACE MR0175/ISO15156 operational service limits among others. The later raw-material test implemented in the early 2010s for screening and qualification purposes aims at quantitatively comparing 718 production heats of various origins and with additive manufacturing also generating interests since the early 2010sthe same tests have also beenextended to determine how layer-by-layer deposited materials compare to bar stock materials.

Picture for Degradation of Aerospace Coatings Due to Combined Effects of Mechanical Loading and Environmental Exposure
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Degradation of Aerospace Coatings Due to Combined Effects of Mechanical Loading and Environmental Exposure

Product Number: 51319-13127-SG
Author: Brandi Clark
Publication Date: 2019
$20.00

The most effective means to control atmospheric corrosion of aircraft is through the use of protective coatings. In addition to combating corrosion which represents a risk to the safe operation of an asset there are strong economic and environmental drivers to extend the service life of aerospace coatings. Repair and replacement of protective coatings that no longer meet performance requirements generate a significant volume of environmentally hazardous waste which includes the coating material media used for coating removal as well as the waste materials generated in surface preparation and reapplication of the coating system. Development and selection of durable coating systems have often been limited by the ability to produce service-relevant failures in accelerated laboratory tests. Existing accelerated test techniques do not adequately employ the chemical thermal or mechanical stressors that produce damage mechanisms such as coating cracking at structural discontinuities in airframes. Additionally individual coatings may be qualified separately rather than as part of a multi-layer system. As a result current test methods cannot be used for accurate quantification of coating performance and service life. In this work test methodologies previously described that employ combined environmental and mechanical loading are used to excite relevant failure modes of multi-layer systems such as coating cracking at sealant-filled lap joints. The kinetics of moisture ingress coating cracking and damage progression are quantified throughout static and dynamic mechanical tests performed under cyclic atmospheric conditions using in situ measurements of coating properties. It is observed that the coating barrier properties and cracking are dependent on stress temperature and humidity as well as the interaction effects of these parameters.