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Mercury is a naturally occurring component present in varying concentrations in natural gas fields all over the world. Liquid metal embrittlement (LME) involves penetration of a liquid metal into a solid metal that leads to brittle fracture. In assessing the design of a production facility a test program was established to evaluate the susceptibility of various metallic materials to LME by mercury. The susceptibilities of the alloys were determined using: 1) slow strain rate testing (SSRT) in mercury for screening and 2) subsequent fitness for service testing based on constant load testing (4-point bending) in a simulated service environment. Materials tested included duplex 2205 alloy 625 Alloy 400 316L stainless MP35N Al5083 aluminum alloy and welded alloy 625. Results from these tests indicate that Alloy 400 and Al5083 showed significant LME susceptibility with an average time-to-failure ratio of 0.60 during slow strain rate screening tests. Constant load fitness for service testing resulted in no significant LME cracking in duplex 2205 alloy 625 316L stainless welded alloy 625 and alloy 400 tested at 100% of actual yield strength in a simulated Hg-containing service environment.
This paper reports liquid metal embrittlement (LME) test results for a variety of common oilfield and processing plant alloys exposed to liquid mercuryp across a range of temperatures. Test methods used include slow strain rate testing and C-ring tests.
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Liquid metal embrittlement (LME) involves penetration of a liquid metal into a solid metal that leads to brittle fracture. A test program was established to evaluate the susceptibility of various metallic materials to LME by mercury.
Results of exposing UNS R56404 forging and pipe product forms to liquid mercury over the 25°-232°C range while highly stressed at & beyond the alloy’s yield point via three loading modes are reported. Included are: sustained load 90 day C-ring tests, slow strain rate tensile testing, and rippled slow strain rate cyclic tensile loading.