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Picture for Impact of O2 Content on Corrosion Behavior of X65 Mild Steel in Gaseous, Liquid and Supercritical CO2 environments
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Impact of O2 Content on Corrosion Behavior of X65 Mild Steel in Gaseous, Liquid and Supercritical CO2 environments

Product Number: 51320-14433-SG
Author: Xiu Jiang, Dingrong Qu , Xiaoliang Song
Publication Date: 2020
$20.00

CO2 stream in CCS system usually contains impurities, such as water, O2, SO2, NO2, H2S, and other trace substances, which could pose a threat to internal corrosion and integrity of CO2 transportation pipelines. The general and localized corrosion behavior of API 5L X65 mild steel were evaluated using an autoclave both in water-saturated CO2 and CO2-saturated water environments in the presence of varying concentrations of O2. Experiments were performed at 25 °C and 35 °C, 8 MPa and 35 °C, 4 MPa to simulate the conditions encountered during dense, supercritical and gaseous CO2 transport. General corrosion rates were obtained by weight-loss method. The surface morphology of the coupons was examined by scanning electron microscopy (SEM). Results indicated that general corrosion rates at each O2 concentration in CO2-saturated water environment were much higher than those in water-saturated CO2 environment. The corrosion rates did not increase with increasing O2 concentration from 0 to 2000 ppm; instead the corrosion rate reached a maximum with 1000 ppm O2 at 25 °C, 8 MPa and 50 ppm O2 at 35 °C, 8 MPa in water-saturated CO2 environment and 50 ppm at 25 °C, 8 MPa and 100 ppm at 35 °C, 8 MPa in CO2-saturated water environment. However, the change trend of general corrosion rate with O2 content at 35 °C, 4 MPa was different from that in 25 °C and 35 °C, 8 MPa both in water-saturated CO2 and CO2-saturated water environments. Localized corrosion or general corrosion rate of over 0.1 mm/y was identified at each test condition both in a water-saturated CO2 and CO2-saturated water environments. When O2 was added, coupon surfaces were covered by a more porous corrosion product scale. A final series of tests conducted with the addition of 100 ppm and 2000 ppm O2 in CO2 environment with 60% relative humidity (RH) and 80% RH revealed that no localized corrosion was observed and the general corrosion rates were lower than 0.1 mm/y at 25 °C and 35 °C, 8 

Picture for Effect Of H2S On CO2 Corrosion Of Mild Steel In HPHT Conditions
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Effect Of H2S On CO2 Corrosion Of Mild Steel In HPHT Conditions

Product Number: 51321-16622-SG
Author: Yoon-Seok Choi/ Fernando Farelas/ Luciano Paolinelli/ Srdjan Nesic/ Ahmad Zaki B Abas/ Azmi Mohammed Nor/ Muhammad Firdaus Suhor
Publication Date: 2021
$20.00
Picture for Intergranular Corrosion of Stainless Steel in Nitric Media
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51315-5609-Intergranular Corrosion of Stainless Steel in Nitric Media

Product Number: 51315-5609-SG
ISBN: 5609 2015 CP
Author: Pierre Laghoutaris
Publication Date: 2015
$20.00
Picture for Effects of Chloride on Copper Corrosion in Reducing Conditions
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Effects of Chloride on Copper Corrosion in Reducing Conditions

Product Number: 51319-13134-SG
Author: Xihua He
Publication Date: 2019
$20.00

Nuclear Regulatory Commission (NRC)Washington DC 20555Copper (Cu) is a candidate waste container material for high-level radioactive waste geologic disposal systems located in the saturated zone because of its thermodynamic stability in anoxic water. However chemical species in the groundwater could change its stability and electrochemical properties especially corrosion resistance. This study investigated the role of chloride (Cl–) in Cu corrosion in solutions containing sulfate (SO42–) and Cl– with residual oxygen (O2) concentrations of about 0.1–0.2 ppb at 20 °C and 50 °C. SO42– concentration was kept constant at 2000 ppm while Cl– concentration was varied from 0 to 1000 10000 and 100000 ppm. Electrochemical methods including corrosion potential (Ecorr) monitoring potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) were used to study the electrochemical properties of Cu affecting corrosion resistance.All the results obtained from different methods consistently demonstrate that Cl– and temperature play significant roles in enhancing corrosion of Cu when O2 concentration is extremely low. Ecorr decreased with increasing Cl− concentration and was lower at 50 °C than at 20 °C. During both forward and reverse potentiodynamic polarization scans Ecorr consistently decreased and the current density increased with increasing Cl− concentration. Tafel slopes from the forward scan regions decreased and the exchange current density increased with increasing Cl− concentration. The EIS data differed in solutions with different Cl− concentration levels and they became more complex at elevated temperatures. A layered film structure was inferred from the EIS data. Polarization resistance derived by fitting to the EIS data was lowest at the highest Cl− concentration which is consistent with increasing corrosion rates with increasing Cl− concentration. The detailed results will be discussed in thepaper.This abstract is an independent product of the CNWRA and does not necessarily reflect the views or regulatory position of NRC. The NRC staff views expressed herein are preliminary and do not constitute a final judgment or determination of the matters addressed or of the acceptability of any licensing action that may be under consideration at NRC.

Picture for Corrosion of steel in cracked reinforced concrete pipes
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51312-01752-Corrosion of steel in cracked reinforced concrete pipes

Product Number: 51312-01752-SG
ISBN: 01752 2012 CP
Author: Ezeddin Busba
Publication Date: 2012
$20.00
Picture for 03366 EVALUATION OF VOLATILE CORROSION
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03366 EVALUATION OF VOLATILE CORROSION INHIBITORS IN EMITTERS

Product Number: 51300-03366-SG
ISBN: 03366 2003 CP
Author: Sunil Dhoot
$20.00
Picture for 07576 Corrosion Behavior of Steels in Concentrated NH4HS Environments
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07576 Corrosion Behavior of Steels in Concentrated NH4HS Environments

Product Number: 51300-07576-SG
ISBN: 07576 2007 CP
Author: Hirohito Iwawaki and Kazuhiro Toba
Publication Date: 2007
$20.00
Picture for Corrosion Related Durability Of Steel Reinforcement In A Novel Concrete Material
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Corrosion Related Durability Of Steel Reinforcement In A Novel Concrete Material

Product Number: 51321-16860-SG
Author: Carolina Páez Jiménez; Jitendra Jain; Alberto Sagüés; Christopher L. Alexander
Publication Date: 2021
$20.00
Picture for 01537 MEASURING ANTIFOULANT AND CORROSION
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01537 MEASURING ANTIFOULANT AND CORROSION INHIBITOR EFFECTIVENESS IN THE LAB

Product Number: 51300-01537-SG
ISBN: 01537 2001 CP
Author: Chris Spurrell
$20.00
Picture for 02240 MOLECULAR MODELING OF CORROSION OF IRON...
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02240 MOLECULAR MODELING OF CORROSION OF IRON IN H2S ENVIRONMENTS

Product Number: 51300-02240-SG
ISBN: 02240 2002 CP
Author: S. Ramachandran, M. B. Ward and K. A. Bartrip
$20.00
Picture for 99170 MICROBIOLOGICALLY INFLUENCED CORROSION OF
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99170 MICROBIOLOGICALLY INFLUENCED CORROSION OF COPPER IN GROUND WATER

Product Number: 51300-99170-SG
ISBN: 99170 1999 CP
Author: Takeshi Sakane, Yasushi Kikuchi, Kenji Tohmofo, Maaayoshi Ozawa and Tsuyoshi Kanamaru
$20.00
Picture for Corrosion of Post-Tensioned Tendons in Deficient Grout
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51314-4225-Corrosion of Post-Tensioned Tendons in Deficient Grout

Product Number: 51314-4225-SG
ISBN: 4225 2014 CP
Author: Kingsley Lau
Publication Date: 2014
$0.00
Picture for 03178 EXPERIENCES IN ASSESSING INTERNAL
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03178 EXPERIENCES IN ASSESSING INTERNAL CORROSION FOR MULTIPHASE FLOW PIPELINES

Product Number: 51300-03178-SG
ISBN: 03178 2003 CP
Author: Carlos A. Palacios T., Danielli Quintero
$20.00
Picture for Corrosion Resistance Of Stainless Steels And Nickel Alloys In Natural Seawater
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Corrosion Resistance Of Stainless Steels And Nickel Alloys In Natural Seawater

Product Number: 51321-16515-SG
Author: Sandra Le Manchet/ Martin Monnot/ Emilie Robin
Publication Date: 2021
$20.00
Picture for 10234 Urex+ Centrifugal Contactor Corrosion in HN03-HF Aqueous Solutions
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10234 Urex+ Centrifugal Contactor Corrosion in HN03-HF Aqueous Solutions

Product Number: 51300-10234-SG
ISBN: 10234 2010 CP
Author: Negin Jahangiri, A.G. Raraz, J.E. Indacochea and S.M. McDeavitt
Publication Date: 2010
$20.00
Picture for Corrosion rates of carbon steel in confined environments
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51312-01495-Corrosion rates of carbon steel in confined environments

Product Number: 51312-01495-SG
ISBN: 01495 2012 CP
Author: Adam Rubin
Publication Date: 2012
$20.00